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Silver-Promoted Oxidative Cyclization of 1,6-Enynes: Highly Regioselective Synthesis of Phosphorated Fluorene Derivatives
Department固体润滑国家重点实验室
Zhou, Zhao-Zhao1; Jin, Dong-Po1; Li, Lian-Hua1; He, Yu-Tao1; Zhou, Ping-Xin1; Yan, Xiao-Biao1; Liu XY(刘雪原)1; Liang YM(梁永民)1,2; Liang YM(梁永民)
2014
Source PublicationOrganic Letters
ISSN1523-7060
Volume16Issue:21Pages:5616-5619
Abstract

A silver-promoted oxidative cyclization of 1,6-enynes with disubstituted phosphine oxides is developed for the synthesis of fluorene derivatives. The reaction proceeds with high regioselectivity by constructing one C–P bond and two C–C bonds in one step. Moreover, reduction of the pentavalent phosphine enlarges the application scope of the product.

Subject Area材料科学与物理化学
DOI10.1021/ol502397f
Funding Organizationthe National Natural Science Foundation (NSF 21272101;201302076);the National Basic Research Program of China (973 Program, 2010CB8-33203);the Fundamental Research Funds for Central Universities (lzujbky-2014-194;lzujbky-2014-243);the "111" Project;Program for Changjiang Scholars and Innovative Research Team in University (IRT1138)
Indexed BySCI
If6.364
Language英语
compositor第二作者单位
Citation statistics
Cited Times:75[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21246
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorLiang YM(梁永民)
Affiliation1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Zhao-Zhao,Jin, Dong-Po,Li, Lian-Hua,et al. Silver-Promoted Oxidative Cyclization of 1,6-Enynes: Highly Regioselective Synthesis of Phosphorated Fluorene Derivatives[J]. Organic Letters,2014,16(21):5616-5619.
APA Zhou, Zhao-Zhao.,Jin, Dong-Po.,Li, Lian-Hua.,He, Yu-Tao.,Zhou, Ping-Xin.,...&梁永民.(2014).Silver-Promoted Oxidative Cyclization of 1,6-Enynes: Highly Regioselective Synthesis of Phosphorated Fluorene Derivatives.Organic Letters,16(21),5616-5619.
MLA Zhou, Zhao-Zhao,et al."Silver-Promoted Oxidative Cyclization of 1,6-Enynes: Highly Regioselective Synthesis of Phosphorated Fluorene Derivatives".Organic Letters 16.21(2014):5616-5619.
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