| Palladium-Catalyzed Insertion of an Allene into an Aminal: Aminomethylamination of Allenes by C-N Bond Activation | |
| Department | OSSO国家重点实验室 |
Hu JH(胡建华)1; Xie YJ(谢银君)2; Huang HM(黄汉民)1,2 ; Huang HM(黄汉民)
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| 2014 | |
| Source Publication | Angewandte Chemie International Edition
 |
| ISSN | 1433-7851 |
| Volume | 53Issue:28Pages:7272-7276 |
| Abstract |
A new and atom-economic palladium-catalyzed aminomethylamination of allenes with aminals by C |
| Keyword | Allenes Aminals C-n Activation Diamines Palladium |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/anie.201403774 |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21172226;21133011) |
| Indexed By | SCI |
| If | 11.261 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/21235 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民) |
| Affiliation | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310024, Zhejiang, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Hu JH,Xie YJ,Huang HM,et al. Palladium-Catalyzed Insertion of an Allene into an Aminal: Aminomethylamination of Allenes by C-N Bond Activation[J]. Angewandte Chemie International Edition,2014,53(28):7272-7276. |
| APA | Hu JH,Xie YJ,Huang HM,&黄汉民.(2014).Palladium-Catalyzed Insertion of an Allene into an Aminal: Aminomethylamination of Allenes by C-N Bond Activation.Angewandte Chemie International Edition,53(28),7272-7276. |
| MLA | Hu JH,et al."Palladium-Catalyzed Insertion of an Allene into an Aminal: Aminomethylamination of Allenes by C-N Bond Activation".Angewandte Chemie International Edition 53.28(2014):7272-7276. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Hu_et_al-2014-Angewa（451KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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N bond activation is described. This direct and operationally simple method provides a fundamentally novel approach for the synthesis of 1,3-diamines. Mechanistic studies suggest that a unique cationic π-allylpalladium complex containing an aminomethyl moiety is generated as a key intermediate through the carbopalladation of the allene with a cyclometalated palladium–alkyl species.
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