Effect of polytetrafluoroethylene gradient-distribution on the hydrophobic and tribological properties of polyphenylene sulfide composite coating | |
Department | 固体润滑国家重点实验室 ; 先进润滑与防护材料研究发展中心 |
Luo ZZ(罗莊竹); Zhang ZZ(张招柱); Wang WJ(王文静); Liu WM(刘维民) | |
2009 | |
Source Publication | Surface & Coatings Technology |
ISSN | 0257-8972 |
Volume | 203Pages:1516-1522 |
Abstract | PTFE/PPS composite coating was prepared on stainless steel block by spraying and curing at high temperature. The hydrophobic properties and tribological performances of the coatings were measured with CA-A contact angle meter and evaluated on a ring-on-block wear tester, respectively. Moreover, the worn surfaces of the PPS composite coating and the transfer films formed on the surface of the counterpart ring were investigated by SEM and optical microscope (OM), respectively. FTIR and XPS analyses were performed to detect the element gradient-distribution and chemical changes of the PTFE/PPS composite coating. It was concluded that during the curing process, PTFE macromolecule chain shifted gradually from coating interior to the surface, resulting in fluorine (F) enrichment on the top surface. The gradient distribution of fluorine led to the possession of both good hydrophobic property and strong adhesive strength of the PTFE/PPS composite coatings. XPS analyses indicated that the high shear force led to decomposition and oxidation of the element of S in the PTFE/PPS coating; and the generated active S reacted tribochemically with counterface Fe, atmospheric O and H2O to form FeSO4 or Fe2(SO4)3. |
Keyword | Composite Coatings Hydrophobic And Tribological Properties Polyphenylene Sulfide (Pps) Polytetrafluoroethylene (Ptfe) Gradient-distribution Tribochemistry |
Subject Area | 材料科学与物理化学 |
Funding Organization | the National 973 project (No. 2007 CB607601);the Innovative Group Foundation of NSFC (Grant No. 50721062);the National Natural Science Foundation of China (No.50835009) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 复合润滑材料组 ; 空间润滑材料组 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/2122 |
Collection | 固体润滑国家重点实验室(LSL) 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 |
Corresponding Author | Zhang ZZ(张招柱); Liu WM(刘维民) |
Recommended Citation GB/T 7714 | Luo ZZ,Zhang ZZ,Wang WJ,et al. Effect of polytetrafluoroethylene gradient-distribution on the hydrophobic and tribological properties of polyphenylene sulfide composite coating[J]. Surface & Coatings Technology,2009,203:1516-1522. |
APA | 罗莊竹,张招柱,王文静,&刘维民.(2009).Effect of polytetrafluoroethylene gradient-distribution on the hydrophobic and tribological properties of polyphenylene sulfide composite coating.Surface & Coatings Technology,203,1516-1522. |
MLA | 罗莊竹,et al."Effect of polytetrafluoroethylene gradient-distribution on the hydrophobic and tribological properties of polyphenylene sulfide composite coating".Surface & Coatings Technology 203(2009):1516-1522. |
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