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Stannous sulfide/multi-walled carbon nanotube hybrids as high-performance anode materials of lithium-ion batteries
Department固体润滑国家重点实验室
Li SK(李栓魁)1; Zuo, Shiyong1; Wu ZG(吴志国)1; Liu, Ying1; Zhuo RF(卓仁富)1; Feng JJ(冯娟娟)1; Yan D(闫德)1; Wang J(王君)1; Yan PX(阎鹏勋)1,2; Wu ZG(吴志国)
2014
Source PublicationElectrochimica Acta
ISSN0013-4686
Volume136Pages:355-362
Abstract

A hybrid of multi-walled carbon nanotubes (MWCNTs) anchored with SnS nanosheets is synthesized through a simple solvothermal method for the first time. Interestingly, SnS can be controllably deposited onto the MWCNTs backbone in the shape of nanosheets or nanoparticles to form two types of SnS/MWCNTs hybrids, SnS NSs/MWCNTs and SnS NPs/MWCNTs. When evaluated as an anode material for lithium-ion batteries, the hybrids exhibit higher lithium storage capacities and better cycling performance compared to pure SnS. It is found that the SnS NSs/MWCNTs hybrid exhibits a large reversible capacity of 620mAhg−1 at a current of 100mAg−1 as an anode material for lithium-ion batteries, which is better than SnS NPs/MWCNTs. The improved performance may be attributed to the ultrathin nanosheet subunits possess short distance for Li+ ions diffusion and large electrode-electrolyte contact area for high Li+ ions flux across the interface. It is believed that the structural design of electrodes demonstrated in this work will have important implications on the fabrication of high-performance electrode materials for lithium-ion batteries.

KeywordSolvothermal Stannous Sulfide Multi-walled Carbon Nanotubes Hybrids Lithium-ion Battery
Subject Area材料科学与物理化学
DOI10.1016/j.electacta.2014.05.080
Funding Organizationthe National Natural Science Foundation of China (Grant No.11004089;11204114);the basic scientific research business expenses of the central university (lzujbky-2013-185);Open Project of Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University (LZUMMM2013013;LZUMMM2014013)
Indexed BySCI
If4.504
Language英语
compositor第二作者单位
Citation statistics
Cited Times:36[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21228
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorWu ZG(吴志国)
Affiliation1.Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Gansu, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Li SK,Zuo, Shiyong,Wu ZG,et al. Stannous sulfide/multi-walled carbon nanotube hybrids as high-performance anode materials of lithium-ion batteries[J]. Electrochimica Acta,2014,136:355-362.
APA Li SK.,Zuo, Shiyong.,Wu ZG.,Liu, Ying.,Zhuo RF.,...&吴志国.(2014).Stannous sulfide/multi-walled carbon nanotube hybrids as high-performance anode materials of lithium-ion batteries.Electrochimica Acta,136,355-362.
MLA Li SK,et al."Stannous sulfide/multi-walled carbon nanotube hybrids as high-performance anode materials of lithium-ion batteries".Electrochimica Acta 136(2014):355-362.
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