The fracture mechanism and the corresponding optimization strategy for nonhydrogenated amorphous carbon film in dimethyl silicone oil
Department先进润滑与防护材料研究发展中心
Tang JZ(汤金柱)1,2; Ding Q(丁奇)1,3; Zhang SW(张松伟)1,3; Hu LT(胡丽天)1; Ding Q(丁奇); Hu LT(胡丽天)
The second department固体润滑国家重点实验室
2016
Source PublicationSurface and Coatings Technology
ISSN0257-8972
Volume307Pages:941-950
Abstract

The synergetic lubrication effects between amorphous carbon (a-C) films and lubricating oils have drawn much attention for the past decades, and related researches suggest that the molecular structure and physicochemical properties of base oil could strongly affect the tribological behavior of a-C films. Here, we report a unique tribological behavior of nonhydrogenated a-C film when slides against the steel counter-parts in polydimethylsiloxane (PDMS), where the a-C film is severely fractured at the onset of sliding, but achieves a very low steady friction coefficient which is only about 50% of the one obtained in the poly-alpha-olefin (PAO). Via detailed morphological, chemical analysis and designed verification experiment, it is proposed that the initial high adhesion between a-C and steel in PDMS accounts for the fracture failure of the analyzed a-C film, while the chemical adsorption of decomposed PDMS on a-C surface is responsible for the reduced friction. Finally, we present an effective method to eliminate the cracking behavior while retain the low friction performance for steel/a-C contacts in PDMS.

KeywordA-c Film Silicone Oil Synergetic Lubrication Design Fracture And Delamination
Subject Area材料科学与物理化学
DOI10.1016/j.surfcoat.2016.10.001
Funding Organizationthe National Natural Science Foundation of China (Grant No. 51575506);Applied Basic Research Project of Qingdao: Youth Program (Grant No. 14-2-4-85-JCH)
Indexed BySCI
If2.589
Language英语
Funding Project特种油脂和密封材料组
compositor第一作者单位
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21210
Collection中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心
固体润滑国家重点实验室(LSL)
Corresponding AuthorDing Q(丁奇); Hu LT(胡丽天)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou, Peoples R China
2.Univ Chinese Acad Sci, Beijing, Peoples R China
3.Qingdao Ctr Resource Chem & New Mat, Qingdao, Peoples R China
Recommended Citation
GB/T 7714
Tang JZ,Ding Q,Zhang SW,et al. The fracture mechanism and the corresponding optimization strategy for nonhydrogenated amorphous carbon film in dimethyl silicone oil[J]. Surface and Coatings Technology,2016,307:941-950.
APA Tang JZ,Ding Q,Zhang SW,Hu LT,丁奇,&胡丽天.(2016).The fracture mechanism and the corresponding optimization strategy for nonhydrogenated amorphous carbon film in dimethyl silicone oil.Surface and Coatings Technology,307,941-950.
MLA Tang JZ,et al."The fracture mechanism and the corresponding optimization strategy for nonhydrogenated amorphous carbon film in dimethyl silicone oil".Surface and Coatings Technology 307(2016):941-950.
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