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Synthesis and characterization of chitosan-g-poly(acrylic acid)/sodiumhumatesuperabsorbent
Department环境材料与生态化学研究发展中心
Liu JH(刘江华); Wang Q(汪琴); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn
2007
Source PublicationCarbohydrate Polymers
ISSN0144-8617
Volume70Issue:2Pages:166-173
AbstractA novel chitosan-g-poly(acrylic acid)/sodiumhumate (CTS-g-PAA/SH) multifunctional superabsorbent was prepared by graft polymerization among chitosan, acrylic acid and sodiumhumate in aqueous solution, using N,N′-methylenebisacrylamide as a crosslinker and ammonium persulfate as an initiator. And the samples were further characterized by means of FTIR, SEM and TGA. The effect of polymerization variables, including reaction temperature, content of initiator, crosslinker and sodiumhumate, the weight ratio of acrylic acid to chitosan, on water absorbency were studied. The swelling rate in distilled water and the swelling behavior in various pH value solutions were also investigated. The result from FTIR spectra showed that chitosan and sodiumhumate participated in graft polymerization reaction with acrylic acid. The introduced sodiumhumate could enhance water absorbency and the content of 10 wt% sodiumhumate gave the best absorption (183 g g?1 in distilled water and 41 g g?1 in 0.9 wt% NaCl solution).
KeywordChitosan Sodiumhumate Superabsorbent Water Absorbency Swelling Behavior
Subject Area功能高分子
Funding Organization国家863计划项目(2006AA03Z0454);中国科学院“西部行动”项目(KGCX2-YW-501)
Indexed BySCI
Language英语
Funding Project功能复合材料组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/211
Collection环境材料与生态化学研究发展中心
Corresponding Author王爱勤 aqwang@licp.cas.cn
Recommended Citation
GB/T 7714
Liu JH,Wang Q,Wang AQ,et al. Synthesis and characterization of chitosan-g-poly(acrylic acid)/sodiumhumatesuperabsorbent[J]. Carbohydrate Polymers,2007,70(2):166-173.
APA 刘江华,汪琴,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2007).Synthesis and characterization of chitosan-g-poly(acrylic acid)/sodiumhumatesuperabsorbent.Carbohydrate Polymers,70(2),166-173.
MLA 刘江华,et al."Synthesis and characterization of chitosan-g-poly(acrylic acid)/sodiumhumatesuperabsorbent".Carbohydrate Polymers 70.2(2007):166-173.
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