Nitrogen Dioxide Catalyzed Oxidative Thiocyanation of Arenes with Ambient Air as the Terminal Oxidant | |
Department | OSSO国家重点实验室 |
Ren, Yun-Lai1; Wang, Wenhui1; Zhao, Bo1; Tian, Xinzhe1; Zhao, Shuang1; Wang, Jianji2; Li FW(李福伟)3 | |
2016 | |
Source Publication | ChemCatChem |
ISSN | 1867-3880 |
Volume | 8Issue:21Pages:3361-3366 |
Abstract | NO2 is an effective catalyst for the oxidative thiocyanation of arenes. This unique catalyst is inexpensive and separated easily from the final products because of its low boiling point. The mild reaction conditions allow a series of arenes and thiophenes to be thiocyanated smoothly in moderate to high yields. A preliminary mechanistic investigation suggests that the present reaction may proceed through a radical pathway. |
Keyword | Arenes Oxidation Oxygen Radicals Reaction Mechanisms |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/cctc.201600785 |
Funding Organization | the Program for Science & Technology Innovation Talents in Universities of Henan Province (Grant No. 15HASTIT004);the Open Project of State Key Laboratory for Oxo Synthesis and Selective Oxidation (Grant No. OSSO-2015-21) |
Indexed By | SCI |
If | 4.803 |
Language | 英语 |
Funding Project | 均相催化课题组 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21198 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Ren, Yun-Lai; Wang, Jianji |
Affiliation | 1.Henan Univ Sci & Technol, Sch Chem Engn & Pharmaceut, Luoyang 471003, Henan, Peoples R China 2.Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Ren, Yun-Lai,Wang, Wenhui,Zhao, Bo,et al. Nitrogen Dioxide Catalyzed Oxidative Thiocyanation of Arenes with Ambient Air as the Terminal Oxidant[J]. ChemCatChem,2016,8(21):3361-3366. |
APA | Ren, Yun-Lai.,Wang, Wenhui.,Zhao, Bo.,Tian, Xinzhe.,Zhao, Shuang.,...&Li FW.(2016).Nitrogen Dioxide Catalyzed Oxidative Thiocyanation of Arenes with Ambient Air as the Terminal Oxidant.ChemCatChem,8(21),3361-3366. |
MLA | Ren, Yun-Lai,et al."Nitrogen Dioxide Catalyzed Oxidative Thiocyanation of Arenes with Ambient Air as the Terminal Oxidant".ChemCatChem 8.21(2016):3361-3366. |
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LZ01029650.pdf(666KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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