LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Nitrogen Dioxide Catalyzed Oxidative Thiocyanation of Arenes with Ambient Air as the Terminal Oxidant
DepartmentOSSO国家重点实验室
Ren, Yun-Lai1; Wang, Wenhui1; Zhao, Bo1; Tian, Xinzhe1; Zhao, Shuang1; Wang, Jianji2; Li FW(李福伟)3
2016
Source PublicationChemCatChem
ISSN1867-3880
Volume8Issue:21Pages:3361-3366
Abstract

NO2 is an effective catalyst for the oxidative thiocyanation of arenes. This unique catalyst is inexpensive and separated easily from the final products because of its low boiling point. The mild reaction conditions allow a series of arenes and thiophenes to be thiocyanated smoothly in moderate to high yields. A preliminary mechanistic investigation suggests that the present reaction may proceed through a radical pathway.

KeywordArenes Oxidation Oxygen Radicals Reaction Mechanisms
Subject Area物理化学与绿色催化
DOI10.1002/cctc.201600785
Funding Organizationthe Program for Science & Technology Innovation Talents in Universities of Henan Province (Grant No. 15HASTIT004);the Open Project of State Key Laboratory for Oxo Synthesis and Selective Oxidation (Grant No. OSSO-2015-21)
Indexed BySCI
If4.803
Language英语
Funding Project均相催化课题组
compositor第三作者单位
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21198
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorRen, Yun-Lai; Wang, Jianji
Affiliation1.Henan Univ Sci & Technol, Sch Chem Engn & Pharmaceut, Luoyang 471003, Henan, Peoples R China
2.Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Ren, Yun-Lai,Wang, Wenhui,Zhao, Bo,et al. Nitrogen Dioxide Catalyzed Oxidative Thiocyanation of Arenes with Ambient Air as the Terminal Oxidant[J]. ChemCatChem,2016,8(21):3361-3366.
APA Ren, Yun-Lai.,Wang, Wenhui.,Zhao, Bo.,Tian, Xinzhe.,Zhao, Shuang.,...&Li FW.(2016).Nitrogen Dioxide Catalyzed Oxidative Thiocyanation of Arenes with Ambient Air as the Terminal Oxidant.ChemCatChem,8(21),3361-3366.
MLA Ren, Yun-Lai,et al."Nitrogen Dioxide Catalyzed Oxidative Thiocyanation of Arenes with Ambient Air as the Terminal Oxidant".ChemCatChem 8.21(2016):3361-3366.
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