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Supramolecular ionogel lubricants with imidazolium-based ionic liquids bearing the urea group as gelator
Department固体润滑国家重点实验室
Yu QL(于强亮); Wu Y(吴杨); Li DM(李冬梅); Cai MR(蔡美荣); Zhou F(周峰); Liu WM(刘维民); Cai MR(蔡美荣); Zhou F(周峰)
2017
Source PublicationJournal of Colloid and Interface Science
ISSN0021-9797
Volume487Pages:130-140
Abstract

A new class of ionic liquid gels (ionogels) is prepared through the supramolecular self-assembly of imidazolium-based ionic liquids (ILs) bearing the urea group as gelators in normal ILs. The ILs gelator can self-assemble through hydrogen bonding and hydrophobic interaction to form analogous lamellar structures and solidify base ILs. The obtained ionogels exhibit superior anticorrosion and conductivity characteristics. Moreover, ionogels show fully thermoreversible and favorable thixotropic characteristics, such that they can be used as high-performance semisolid conductive lubricants. The tribological tests reveal that these ionogels lubricants can effectively reduce the friction of sliding pairs effectively and have better tribological performance than the pure ILs under harsh conditions. Ionogel lubricants not only maintain the excellent tribological properties and conductivity of ILs, but also prevent base liquids from creeping and leakage. Therefore, ionogel lubricants can be potentially used in the conductive parts of electrical equipments.

KeywordSupramolecular Ionogel Thixotropic Lubricant Anti-corrosion Friction Reduction Anti-wear
Subject Area材料科学与物理化学
DOI10.1016/j.jcis.2016.10.020
Funding Organizationthe NSFC (51675512;51305428;51227804);“973” Program (2013CB632301)
Indexed BySCI
If4.233
Language英语
Funding Project材料表面与界面行为研究组;空间润滑材料组
compositor第一作者单位
Citation statistics
Cited Times:46[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21190
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorCai MR(蔡美荣); Zhou F(周峰)
AffiliationChinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Yu QL,Wu Y,Li DM,et al. Supramolecular ionogel lubricants with imidazolium-based ionic liquids bearing the urea group as gelator[J]. Journal of Colloid and Interface Science,2017,487:130-140.
APA Yu QL.,Wu Y.,Li DM.,Cai MR.,Zhou F.,...&周峰.(2017).Supramolecular ionogel lubricants with imidazolium-based ionic liquids bearing the urea group as gelator.Journal of Colloid and Interface Science,487,130-140.
MLA Yu QL,et al."Supramolecular ionogel lubricants with imidazolium-based ionic liquids bearing the urea group as gelator".Journal of Colloid and Interface Science 487(2017):130-140.
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