Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids

doi:10.1021/acs.organomet.6b00638

	Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids
Department	OSSO国家重点实验室
	Zhou H(周慧)1,2; Zhang JL(张金龙)1; Yang HM(杨化萌)1; Xia CG(夏春谷)1 ; Jiang GX(蒋高喜)1; Jiang GX(蒋高喜)
	2016
Source Publication	Organometallics
ISSN	0276-7333
Volume	35 Issue:19 Pages:3406-3412
Abstract	An unprecedented rhodium-catalyzed selective cleavage of double alkyl-oxygen bonds of bis/tris(o-alkyloxyphenyl)phosphine has been realized, in which P atom functions as a directing group and simple aryl acids are the methyl group acceptor to provide methyl esters and a quaternary phosphonium salt. The preliminary mechanism was investigated via an ¹⁸O labeling experiment and stoichiometric reaction between a Rh-A crystal and an aromatic acid.
Subject Area	物理化学与绿色催化
DOI	10.1021/acs.organomet.6b00638
Funding Organization	the Hundred Talent Program of Chinese Academy of Sciences (CAS);the Natural Science Foundation of Jiangsu (Grant No. BK20151235)
Indexed By	SCI
If	3.862
Language	英语
Funding Project	均相催化课题组
compositor	第一作者单位
Citation statistics	Cited Times:6[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/21039
Collection	羰基合成与选择氧化国家重点实验室（OSSO）苏州研究院
Corresponding Author	Jiang GX(蒋高喜)
Affiliation	1.Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation GB/T 7714	Zhou H,Zhang JL,Yang HM,et al. Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids[J]. Organometallics,2016,35(19):3406-3412.
APA	Zhou H,Zhang JL,Yang HM,Xia CG,Jiang GX,&蒋高喜.(2016).Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids.Organometallics,35(19),3406-3412.
MLA	Zhou H,et al."Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids".Organometallics 35.19(2016):3406-3412.

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