Mesoporous Ni-doped MnCo2O4 hollow nanotubes as an anode material for sodium ion batteries with ultralong life and pseudocapacitive mechanism | |
Department | 清洁能源化学与材料实验室 |
Wu LJ(吴利军)1,2; Lang JW(郎俊伟)1; Zhang P(张鹏)1,2; Zhang X(张旭)1; Guo RS(郭瑞生)1; Yan XB(阎兴斌)1; Yan XB(阎兴斌) | |
The second department | 固体润滑国家重点实验室 |
2016 | |
Source Publication | Journal of Materials Chemistry A |
ISSN | 2050-7488 |
Volume | 4Issue:47Pages:18392-18400 |
Abstract | Mesoporous Ni-doped MnCo2O4 hollow nanotubes (denoted as MCNO-HNTs) are successfully prepared through simple single-nozzle electrospinning combined with thermal treatment. MCNO-HNTs obviously exhibit a hollow structure and are assembled by a lot of small nanoparticles. When used as an anode material for sodium-ion batteries (SIBs), this electrode exhibits remarkable capacity retention of 81% at 1 A g−1 even after 11000 cycles. The outstanding electrochemical performance can be attributed to the unique hollow mesoporous structure that alleviates stress caused by large volume changes, suppresses the agglomeration of the pulverized nanoparticles, and facilitates the transfer of electrons and electrolyte ions during prolonged cycling. Furthermore, the pseudocapacitive behavior of this material also effectively improves the electrochemical reaction kinetics. Therefore, due to the simple single-nozzle electrospinning technique and high electrochemical performance, mesoporous MCNO-HNTs have great potential as an anode material for rechargeable SIBs. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1039/c6ta08364a |
Funding Organization | the National Nature Science Foundation of China (21573265;21673263;51501208) |
Indexed By | SCI |
If | 8.867 |
Language | 英语 |
Funding Project | 低维材料与化学储能课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21000 |
Collection | 清洁能源化学与材料实验室 固体润滑国家重点实验室(LSL) |
Corresponding Author | Yan XB(阎兴斌) |
Affiliation | 1.Laboratory of Clean Energy Chemistry and Materials, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China 2.University of Chinese Academy of Sciences, Beijing, P. R. China |
Recommended Citation GB/T 7714 | Wu LJ,Lang JW,Zhang P,et al. Mesoporous Ni-doped MnCo2O4 hollow nanotubes as an anode material for sodium ion batteries with ultralong life and pseudocapacitive mechanism[J]. Journal of Materials Chemistry A,2016,4(47):18392-18400. |
APA | Wu LJ.,Lang JW.,Zhang P.,Zhang X.,Guo RS.,...&阎兴斌.(2016).Mesoporous Ni-doped MnCo2O4 hollow nanotubes as an anode material for sodium ion batteries with ultralong life and pseudocapacitive mechanism.Journal of Materials Chemistry A,4(47),18392-18400. |
MLA | Wu LJ,et al."Mesoporous Ni-doped MnCo2O4 hollow nanotubes as an anode material for sodium ion batteries with ultralong life and pseudocapacitive mechanism".Journal of Materials Chemistry A 4.47(2016):18392-18400. |
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