| Effective synthesis of dimethylhexane-1,6-dicarbamate from 1,6-hexanediamine and dimethyl carbonate using 3-amino-1,2,4-triazole potassium as a solid base catalyst at ambient temperature | |
| Department | OSSO国家重点实验室 |
Wang PX(王培学)1,2 ; Fei YQ(费玉清)1; Li QH(李庆贺)1; Deng YQ(邓友全)1,2; Deng YQ(邓友全)
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| The second department | 固体润滑国家重点实验室 |
| 2016 | |
| Source Publication | Green Chemistry
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| ISSN | 1463-9262 |
| Volume | 18Issue:24Pages:6681-6686 |
| Abstract | A new basic catalyst 3-amino-1,2,4-triazole potassium (KATriz) was prepared, characterized and employed for synthesis of dimethylhexane 1,6-dicarbamate (MHDC) by methoxycarbonylation of 1,6-hexanediamine (HDA) and dimethyl carbonate (DMC). Results showed that KATriz exhibited high catalytic activity and selectivity, 100% HDA conversion with nearly 100% MHDC selectivity that could be obtained at room temperature. The catalyst can be reused for several runs without any deactivation. Besides, the influence of reaction conditions, the structure of amines and the possible catalytic mechanism were also investigated. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c6gc02509a |
| Funding Organization | the National Natural Science Foundation of China (No. 21173240) |
| Indexed By | SCI |
| If | 9.125 |
| Language | 英语 |
| Funding Project | 绿色催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20998 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Deng YQ(邓友全) |
| Affiliation | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China 2.Qingdao Center of Resource Chemistry & New Materials, Qingdao, China |
| Recommended Citation GB/T 7714 | Wang PX,Fei YQ,Li QH,et al. Effective synthesis of dimethylhexane-1,6-dicarbamate from 1,6-hexanediamine and dimethyl carbonate using 3-amino-1,2,4-triazole potassium as a solid base catalyst at ambient temperature[J]. Green Chemistry,2016,18(24):6681-6686. |
| APA | Wang PX,Fei YQ,Li QH,Deng YQ,&邓友全.(2016).Effective synthesis of dimethylhexane-1,6-dicarbamate from 1,6-hexanediamine and dimethyl carbonate using 3-amino-1,2,4-triazole potassium as a solid base catalyst at ambient temperature.Green Chemistry,18(24),6681-6686. |
| MLA | Wang PX,et al."Effective synthesis of dimethylhexane-1,6-dicarbamate from 1,6-hexanediamine and dimethyl carbonate using 3-amino-1,2,4-triazole potassium as a solid base catalyst at ambient temperature".Green Chemistry 18.24(2016):6681-6686. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| GC-DMC-MHDC.pdf（1032KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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