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Tribological characteristics of bisphenol S bis(diphenyl phosphate) as a high-performance antiwear additive in lubricating greases at elevated temperature
Department固体润滑国家重点实验室
Zhu LL(朱丽丽)1,2; Wu XH(吴新虎)1,2; Zhao GQ(赵改青)1; Wang XB(王晓波)1
2016
Source PublicationLubrication Science
ISSN0954-0075
Volume28Issue:7Pages:433-448
Abstract

Bisphenol S bis(diphenyl phosphate) (BSDP) was synthesised and characterised, and its tribological behaviours as additives in polyurea grease and lithium complex grease were evaluated for steel/steel contact at 200 °C. The results indicated that BSDP could dramatically reduce the friction and wear of sliding pairs in the base grease of polyurea, and the tribological performances of BSDP in polyurea grease were significantly superior to the normally used molybdenum disulfide-based additive package. Furthermore, BSDP in polyurea grease has better tribological behaviour than that in lithium complex grease at a constant load of 100 N. X-ray photoelectron spectroscopy analysis indicated that boundary lubrication films composed of Fe(OH)O, Fe2O3, Fe3O4 and FePO4 compounds containing the P–O bonds and nitride compounds were formed on the worn surface, which resulted in excellent friction reduction and antiwear performance.

KeywordBisphenol s Bis(Diphenyl Phosphate) Polyurea Grease Lithium Complex Grease Antiwear Additives
Subject Area材料科学与物理化学
DOI10.1002/ls.1340
Funding Organizationthe Major State Basic Research Development Program in China (973 Program) (grant no. 2013CB632301);NSFC (51475445)
Indexed BySCI
If1.414
Language英语
Funding Project工业润滑研究组
compositor第一作者单位
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/20993
Collection固体润滑国家重点实验室(LSL)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhu LL,Wu XH,Zhao GQ,et al. Tribological characteristics of bisphenol S bis(diphenyl phosphate) as a high-performance antiwear additive in lubricating greases at elevated temperature[J]. Lubrication Science,2016,28(7):433-448.
APA Zhu LL,Wu XH,Zhao GQ,&Wang XB.(2016).Tribological characteristics of bisphenol S bis(diphenyl phosphate) as a high-performance antiwear additive in lubricating greases at elevated temperature.Lubrication Science,28(7),433-448.
MLA Zhu LL,et al."Tribological characteristics of bisphenol S bis(diphenyl phosphate) as a high-performance antiwear additive in lubricating greases at elevated temperature".Lubrication Science 28.7(2016):433-448.
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