Fabrication of magnetic porous microspheres via (O-1/W)/O-2 double emulsion for fast removal of Cu2+ and Pb2+ | |
Department | 环境材料与生态化学研究发展中心 |
Zhu YF(朱永峰)1,2; Zheng YA(郑易安)1,3; Wang F(王锋)1,2; Wang AQ(王爱勤)1; Zheng YA(郑易安); Wang AQ(王爱勤) | |
2016 | |
Source Publication | Journal of the Taiwan Institute of Chemical Engineers |
ISSN | 1876-1070 |
Volume | 67Pages:505-510 |
Abstract | A series of magnetic porous microspheres were prepared via (O1/W)/O2 double emulsion by grafting acrylic acid (AA) chains onto the backbone of hydroxyl propyl cellulose (HPC). The silane modified Fe3O4 particles and the surfactant polyglycerol polyricinoleate (PGPR) were used to stabilize the internal O1/W Pickering emulsion and the (O1/W)/O2 double emulsion, respectively. The results indicated that the magnetic microspheres with the mean diameter about of 10 μm had interconnected pore structure and the subsequent adsorption experiments demonstrated that the as-prepared magnetic porous microspheres showed the fast adsorption kinetics for removal of Cu2+ and Pb2+, and the adsorption equilibrium can be achieved within 3 min for Cu2+ and 5 min for Pb2+ regardless of higher (400 mg/l) or lower (100 mg/l) initial concentrations. Additionally, the high adsorption capacity with 227.34 mg/g for Cu2+ and 476.85 mg/g for Pb2+ and the excellent reusability by in situ magnetic separation were also presented. Therefore, the magnetic porous microspheres can be applied as a potential recyclable material for highly efficient removal of heavy metals. |
Keyword | Double Emulsion Porous Microsphere Pickering Emulsion Adsorption Magnetic |
Subject Area | 环境材料与生态化学 |
DOI | 10.1016/j.jtice.2016.08.006 |
Funding Organization | the National Natural Science Foundation of China (21377135;21477135;51403221);the Fundamental Research Funds for the Central Universities (No. lzujbky-2015-127) |
Indexed By | SCI |
If | 4.217 |
Language | 英语 |
Funding Project | 功能复合材料组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20989 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | Zheng YA(郑易安); Wang AQ(王爱勤) |
Affiliation | 1.Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Tianshui Middle Road 18, Lanzhou 730000, China 2.Graduate University of the Chinese Academy of Sciences, Beijing 100049, China 3.Gansu Key Laboratory for Environmental Pollution Prediction and Control, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China |
Recommended Citation GB/T 7714 | Zhu YF,Zheng YA,Wang F,et al. Fabrication of magnetic porous microspheres via (O-1/W)/O-2 double emulsion for fast removal of Cu2+ and Pb2+[J]. Journal of the Taiwan Institute of Chemical Engineers,2016,67:505-510. |
APA | Zhu YF,Zheng YA,Wang F,Wang AQ,郑易安,&王爱勤.(2016).Fabrication of magnetic porous microspheres via (O-1/W)/O-2 double emulsion for fast removal of Cu2+ and Pb2+.Journal of the Taiwan Institute of Chemical Engineers,67,505-510. |
MLA | Zhu YF,et al."Fabrication of magnetic porous microspheres via (O-1/W)/O-2 double emulsion for fast removal of Cu2+ and Pb2+".Journal of the Taiwan Institute of Chemical Engineers 67(2016):505-510. |
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