Advances and applications of graphitic carbon nitride as sorbent inanalytical chemistry for sample pretreatment | |
Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Sun YP(孙英佩)1,2; Ha W(哈伟)1; Chen J(陈娟)1; Qi HY(戚欢阳)1; Shi YP(师彦平)1; Qi HY(戚欢阳); Shi YP(师彦平) | |
2016 | |
Source Publication | Trends in Analytical Chemistry |
ISSN | 0165-9936 |
Volume | 84Pages:12-21 |
Abstract | As a green and efficient sorbent, graphitic carbon nitride (g-C3N4) with aromatic tri-s-triazine units has shown great potential for the enrichment or removal of metal ions and organic aromatic compounds, which makes it a promising candidate to complement graphenes in analytical chemistry. The in-built N-rich functional groups and electronic delocalization properties endow g-C3N4 with complex sorption mechanism, containing complexion, hydrogen bond, redox reaction, π – π conjugation, hydrophobic effect, acid-base reaction and electrostatic interaction. The structure and surface physicochemical properties related to the sorption behavior are mainly depended on the preparation and sorption conditions, such as polymerization temperature, polymerization precursors, the solution pH and ionic strength. As a new sorbent, g-C3N4 has been applied to the sample pretreatment in analytical chemistry with solid-phase extraction (SPE), magnetic solid-phase extraction (MSPE), and solid-phase microextraction (SPME) modes, recently. At the same time, a series of modification methods and technologies have been exploited to modify the structural and surface physicochemical properties of g-C3N4, facilitating more effective and selective sorption process. To raise awareness of the superior properties of g-C3N4 and facilitate its applications as a sorbent in analytical chemistry, the sorption properties (sorption mechanism, influence factors of sorption behavior), applications to the sample pretreatment and structural modifications of g-C3N4 are reviewed. |
Keyword | Sorbent Graphitic Carbon Nitride (G-c3n4) Tri-s-triazine Units Metal Ions Aromatic Compounds Analytical Chemistry Sorption Mechanism Modification |
Subject Area | 分析化学与药物化学 |
DOI | 10.1016/j.trac.2016.03.002 |
Funding Organization | the National Natural Science Foundation of China (Nos. 21375136;21105106);the scientific research project of Central Asia Drug Discovery and Development Centre of Chinese Academy of Sciences (No. CAM 201404) |
Indexed By | SCI |
If | 8.442 |
Language | 英语 |
Funding Project | 药物化学成分研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20909 |
Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Corresponding Author | Qi HY(戚欢阳); Shi YP(师彦平) |
Affiliation | 1.Key Laboratory of Chemistry of Northwestern Plant Resources of the CAS and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China 2.University of Chinese Academy of Sciences, Beijing 100039, China |
Recommended Citation GB/T 7714 | Sun YP,Ha W,Chen J,et al. Advances and applications of graphitic carbon nitride as sorbent inanalytical chemistry for sample pretreatment[J]. Trends in Analytical Chemistry,2016,84:12-21. |
APA | Sun YP.,Ha W.,Chen J.,Qi HY.,Shi YP.,...&师彦平.(2016).Advances and applications of graphitic carbon nitride as sorbent inanalytical chemistry for sample pretreatment.Trends in Analytical Chemistry,84,12-21. |
MLA | Sun YP,et al."Advances and applications of graphitic carbon nitride as sorbent inanalytical chemistry for sample pretreatment".Trends in Analytical Chemistry 84(2016):12-21. |
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TrAC-2016(SunYP).pdf(1136KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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