| Synthesis and application of metal-containing ZSM-5 for the selective catalytic reduction of NOx with NH3 | |
| Department | ERC国家工程研究中心 |
Enhui Yuan1,4 ; Kun Zhang2; Lu GX(吕功煊)1; Zunli Mo3; Tang ZC(唐志诚)1; Tang ZC(唐志诚)
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| The second department | osso国家重点实验室 |
| 2016 | |
| Source Publication | Journal of Industrial and Engineering Chemistry
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| ISSN | 1226-086X |
| Volume | 42Pages:142-148 |
| Abstract | We reported a new one-pot method to synthesize Cu incorporated ZSM-5 with ethylene diamine tetraacetic acid copper disodium salt hydrate (EDTA-Cu) as copper source by a hydrothermal process. The obtained isomorphous substituted Cu-ZSM-5 exhibits more excellent reactivity for selective catalytic reduction of NOx by NH3 with long term stability than their conventional copper impregnated counterparts. The results indicate that the tetracoordinated Cu species in the ZSM-5 frameworks have superior catalytic properties than the Cu species existed outside the ZSM-5 zeolites frameworks. The novel ammonium salt complex method was used for the first time to synthesize the metal-ZSM-5 molecular sieves. |
| Keyword | Nh3-scr Reaction Catalytic Reduction Cu-zsm-5 Hydrothermal Stability |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.jiec.2016.07.030 |
| Funding Organization | Science and Technology Service Network Initiative (STS) of Chinese Academy of Science (KFJ-SW-STS-149);the National Basic Research Program of China (2013CB933200);the National Natural Science Foundation of China (21407154;21507137;21573074;21373004);the West Light Foundation of the Chinese Academy of Sciences |
| Indexed By | SCI |
| If | 4.421 |
| Language | 英语 |
| Funding Project | 工业催化课题组;环境催化与氢能源研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20900 |
| Collection | 精细石油化工中间体国家工程研究中心（ERC） 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Tang ZC(唐志诚) |
| Affiliation | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, and National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China 2.Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China 3.College of Chemistry, Northwest Normal University, Lanzhou 730070, China 4.School of Materials Science and Engineering, Nankai University, Tianjin 300071, China |
| Recommended Citation GB/T 7714 | Enhui Yuan,Kun Zhang,Lu GX,et al. Synthesis and application of metal-containing ZSM-5 for the selective catalytic reduction of NOx with NH3[J]. Journal of Industrial and Engineering Chemistry,2016,42:142-148. |
| APA | Enhui Yuan,Kun Zhang,Lu GX,Zunli Mo,Tang ZC,&唐志诚.(2016).Synthesis and application of metal-containing ZSM-5 for the selective catalytic reduction of NOx with NH3.Journal of Industrial and Engineering Chemistry,42,142-148. |
| MLA | Enhui Yuan,et al."Synthesis and application of metal-containing ZSM-5 for the selective catalytic reduction of NOx with NH3".Journal of Industrial and Engineering Chemistry 42(2016):142-148. |
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| Synthesis and applic（1345KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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