| Glycerol as a Building-Block for Prochiral Amino Ketone, N-Formamide and N-Methyl Amine Synthesis | |
| Department | OSSO国家重点实验室 |
Dai XC(代兴超)1,3; Jabor Rabeah2; Yuan HK(袁航空)1 ; Angelika Brückner2; Cui XJ(崔新江)1,2; Shi F(石峰)1; Shi F(石峰)
| |
| 2016 | |
| Source Publication | ChemSusChem
 |
| ISSN | 1864-5631 |
| Volume | 9Issue:22Pages:3133-3138 |
| Abstract | Prochiral aminoketones are key intermediates for the synthesis of optically active amino alcohols, and glycerol is one of the main biomass-based alcohols available in industry. In this work, glycerol was catalytically activated and purposefully converted with amines to generate highly valuable prochiral aminoketones, as well as N-formamides and N-methyl amines, over CuNiAlOx catalyst. The catalyst structure can be anticipated as nano-Ni species on or in CuAlOx via the formation of nano- Cu−Ni alloy particles. This concept may present a novel and valuable methodology for glycerol utilization. |
| Keyword | Alkylation Amination Heterogeneous Catalysis Glycerol Formylation |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/cssc.201600972 |
| Funding Organization | The National Natural Science Foundation of China (21303228);Youth Innovation Promotion Association CAS |
| Indexed By | SCI |
| If | 7.226 |
| Language | 英语 |
| Funding Project | 纳米催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20892 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 绿色化学研究发展中心 |
| Corresponding Author | Angelika Brückner; Shi F(石峰) |
| Affiliation | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation Center for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, No. 18, Tianshui Middle Road, Lanzhou 730000 (China) 2.Leibniz-Institut für katalyse e. V. an der Universitdt Rostock (LIKAT) Albert-Einstein-Strasse 29a, 18059 Rostock (Gemany) 3.University of Chinese Academy of Sciences, No. 19A, Yuquanlu, Beijing, 100049 (China) |
| Recommended Citation GB/T 7714 | Dai XC,Jabor Rabeah,Yuan HK,et al. Glycerol as a Building-Block for Prochiral Amino Ketone, N-Formamide and N-Methyl Amine Synthesis[J]. ChemSusChem,2016,9(22):3133-3138. |
| APA | Dai XC.,Jabor Rabeah.,Yuan HK.,Angelika Brückner.,Cui XJ.,...&石峰.(2016).Glycerol as a Building-Block for Prochiral Amino Ketone, N-Formamide and N-Methyl Amine Synthesis.ChemSusChem,9(22),3133-3138. |
| MLA | Dai XC,et al."Glycerol as a Building-Block for Prochiral Amino Ketone, N-Formamide and N-Methyl Amine Synthesis".ChemSusChem 9.22(2016):3133-3138. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Glycerol as a Buildi（753KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment