Heterogeneous selective synthesis of 1,2-dihydro-1,3,5-triazines from alcohols and amidines via Cu/OMS-2-catalyzed multistep oxidation

doi:10.1016/j.catcom.2016.10.014

	Heterogeneous selective synthesis of 1,2-dihydro-1,3,5-triazines from alcohols and amidines via Cu/OMS-2-catalyzed multistep oxidation
Department	ERC国家工程研究中心
	Meng X(孟旭)1 ; Bi XR(毕秀茹)1; Wang YM(王艳敏)1; Chen GX(陈革新)1 ; Chen BH(陈保华)2; Jing ZQ(景震强)3; Zhao PQ(赵培庆)1 ; Zhao PQ(赵培庆)
The second department	苏州研究院；osso国家重点实验室
	2017
Source Publication	Catalysis Communications
ISSN	1566-7367
Volume	89 Pages:34-39
Abstract	Copper supported on octahedral manganese oxide molecular sieve (OMS-2) which was obtained via reducing KMnO₄ by TBHP was prepared and found to be an efficient catalyst for the synthesis of 1,2-dihydro-1,3,5-triazines directly from alcohols and amidines in one-pot via multistep oxidation. The recyclable heterogeneous catalyst was characterized by BET, XRD, FTIR, TEM and SEM, and the catalytic system can tolerate a wide range of substrates under air with low catalyst loading of supported copper (0.25 mol%), employing OMS-2 as the electron-transfer mediator (ETM) and support.
Keyword	Heterogeneous Catalysis Multistep Oxidation Oms-2 Supported Catalyst Triazine
Subject Area	物理化学与绿色催化
DOI	10.1016/j.catcom.2016.10.014
Funding Organization	the National Natural Science Foundation of China (Grant Nos. 21403256;21573261;21372102);the Suzhou Industrial Technology and Innovation Project (Grant No. SYG201531);the Project of National Science Foundation of Gansu Province (No. 1208RJZA266)
Indexed By	SCI
If	3.330
Language	英语
Funding Project	催化新工艺研究组
compositor	第一作者单位
Citation statistics	Cited Times:21[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/20719
Collection	精细石油化工中间体国家工程研究中心（ERC）羰基合成与选择氧化国家重点实验室（OSSO）
Corresponding Author	Zhao PQ(赵培庆)
Affiliation	1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China 2.State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China 3.Suzhou Institute of Nano-Tech and Nano-Bionic (SINANO), Chinese Academy of Sciences, Suzhou 215123, China
Recommended Citation GB/T 7714	Meng X,Bi XR,Wang YM,et al. Heterogeneous selective synthesis of 1,2-dihydro-1,3,5-triazines from alcohols and amidines via Cu/OMS-2-catalyzed multistep oxidation[J]. Catalysis Communications,2017,89:34-39.
APA	Meng X.,Bi XR.,Wang YM.,Chen GX.,Chen BH.,...&赵培庆.(2017).Heterogeneous selective synthesis of 1,2-dihydro-1,3,5-triazines from alcohols and amidines via Cu/OMS-2-catalyzed multistep oxidation.Catalysis Communications,89,34-39.
MLA	Meng X,et al."Heterogeneous selective synthesis of 1,2-dihydro-1,3,5-triazines from alcohols and amidines via Cu/OMS-2-catalyzed multistep oxidation".Catalysis Communications 89(2017):34-39.

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