Constructing a novel ternary composite (C16H33(CH3)3N)4W10O32/g-C3N4/rGO with enhanced visible-light-driven photocatalytic activity for degradation of dyes and phenol | |
Department | OSSO国家重点实验室 |
Yang XL(杨晓龙)1; Qian, Fangfang1; Wang Y(汪妍)2; Li ML(李孟丽)3; Lu, Jinren1; Li, Yiming1; Bao, Mutai1 | |
2017 | |
Source Publication | Applied Catalysis B: Environmental |
ISSN | 0926-3373 |
Volume | 200Pages:283-296 |
Abstract | The photocatalytic performance of the g-C3N4 photocatalyst was restricted by the low efficiency because of the fast charge recombination. The present work constructed a “killing two birds with one stone” composite (C16H33(CH3)3N)4W10O32/g-C3N4 heterostructured photocatalysts with the aim to greatly promote the charge separation and recycle decatungstate in aqueous solution. Decatungstate was immobilized on g-C3N4 in the form of modified decatungstate (C16H33(CH3)3N)4W10O32 via surface bonding method for the first time. Furthermore, a novel ternary (C16H33(CH3)3N)4W10O32/g-C3N4/rGO photocatalyst was successfully constructed by integrating graphene into the binary (C16H33(CH3)3N)4W10O32/g-C3N4 composite as the electron mediator. The photocatalysts were characterized by XRD, FTIR, FESEM, TEM, UV-vis DRS, PL and EIS measurement. The photocatalytic properties were evaluated in photodecomposition of aqueous methyl orange and phenol under visible-light irradiations. It has been shown that the obtained (C16H33(CH3)3N)4W10O32/g-C3N4 photocatalyst exhibited improved photocatalytic activity and enhanced reduced charge recombination as compared with those of g-C3N4 and (C16H33(CH3)3N)4W10O32. It has been found that the introduction of graphene revealed a synergistic effect between the (C16H33(CH3)3N)4W10O32 species, g-C3N4 and graphene existed in the ternary photocatalyst. Consequently, the photocatalytic activity of the ternary (C16H33(CH3)3N)4W10O32/g-C3N4/rGO photocatalyst was superior to that of the binary one, originating from its stronger visible-light absorption and more reduced charge combination. Finally, recycling experiments revealed that the ternary composite photocatalyst was not only highly efficient but also robust, because it can be used six times without loss of activity, which efficiently solved the problem of recycling decatungstate in reaction system. This work demonstrated that rational design and construction of g-C3N4-decatungstate composites could open up a new avenue for the development of new efficient visible-light photocatalysts for water disinfection. |
Keyword | G-c3n4 Decatungstate Graphene Visible-light-driven Photocatalysis Charge Separation And Transfer |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.apcatb.2016.07.024 |
Funding Organization | the National Natural Science Foundation of China (21403257;41376084);Postdoctoral Research Project of Qingdao, China (861605040004) |
Indexed By | SCI |
If | 9.446 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20695 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Affiliation | 1.Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, 238 Song Ling Rd, Qingdao 266100, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, 18 Tian Shui Rd, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, 1295 Ding Xi Rd, Shanghai 200050, Peoples R China |
Recommended Citation GB/T 7714 | Yang XL,Qian, Fangfang,Wang Y,et al. Constructing a novel ternary composite (C16H33(CH3)3N)4W10O32/g-C3N4/rGO with enhanced visible-light-driven photocatalytic activity for degradation of dyes and phenol[J]. Applied Catalysis B: Environmental,2017,200:283-296. |
APA | Yang XL.,Qian, Fangfang.,Wang Y.,Li ML.,Lu, Jinren.,...&Bao, Mutai.(2017).Constructing a novel ternary composite (C16H33(CH3)3N)4W10O32/g-C3N4/rGO with enhanced visible-light-driven photocatalytic activity for degradation of dyes and phenol.Applied Catalysis B: Environmental,200,283-296. |
MLA | Yang XL,et al."Constructing a novel ternary composite (C16H33(CH3)3N)4W10O32/g-C3N4/rGO with enhanced visible-light-driven photocatalytic activity for degradation of dyes and phenol".Applied Catalysis B: Environmental 200(2017):283-296. |
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