Preparation of CuS with Flower-Like Morphology by Water/Ethanol Solvothermal Synthesis | |
Department | 固体润滑国家重点实验室 |
Li, Maohua1,2,3; Hao JY(郝俊英)3; Lu, Yi1,2; Fan MJ(凡明锦)3; Yang, Bo2; Liu, Yumei1 | |
2016 | |
Source Publication | Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry |
ISSN | 1553-3174 |
Volume | 46Issue:9Pages:1415-1421 |
Abstract | CuS, with a flower-like morphology, has been prepared using a facile solvothermal treatment, with copper chloride (CuCl2.2H2O) and thiourea (CH4N2S) in water and dilute ethanol (water/ethanol = 1/1), at 150°C for 15 h without the assistance of a surfactant. The products were characterized by X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, and UV–vis optical absorption spectroscopy. The resultant CuS flowers, with diameters ˜5 µm, were assembled by sheets. The influences of different solvent systems and varying copper sources on the CuS morphology were also investigated. The results reveal that the hydrophilicity, polarity, and viscosity of the solvent have great influences on the morphology and size of the CuS products. The possible growth mechanisms of flower-like CuS were discussed. The optical properties of the products were also recorded by means of UV-vis absorption spectroscopy. |
Keyword | Copper Sulfide Flower-like Morphology Solvothermal Synthesis Hydrophilic |
Subject Area | 材料科学与物理化学 |
DOI | 10.1080/15533174.2015.1137011 |
Funding Organization | the National Natural Science Foundation of China (No. 51375471);the major project of Xinjiang Bureau of Quality and Technical Supervision (No. 2013-01);the Science and Technology Project of State Quality Inspection Administration (2013QK086) |
Indexed By | SCI |
If | 0.489 |
Language | 英语 |
Funding Project | 空间润滑材料组 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20687 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Liu, Yumei |
Affiliation | 1.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Xinjing, Peoples R China 2.Xinjiang Supervis & Inspect Inst Prod Qual, Urumqi, Xinjing, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou, Peoples R China |
Recommended Citation GB/T 7714 | Li, Maohua,Hao JY,Lu, Yi,et al. Preparation of CuS with Flower-Like Morphology by Water/Ethanol Solvothermal Synthesis[J]. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry,2016,46(9):1415-1421. |
APA | Li, Maohua,Hao JY,Lu, Yi,Fan MJ,Yang, Bo,&Liu, Yumei.(2016).Preparation of CuS with Flower-Like Morphology by Water/Ethanol Solvothermal Synthesis.Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry,46(9),1415-1421. |
MLA | Li, Maohua,et al."Preparation of CuS with Flower-Like Morphology by Water/Ethanol Solvothermal Synthesis".Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 46.9(2016):1415-1421. |
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LZ01029411.pdf(586KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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