MgO-template-assisted synthesis of worm-like carbon@MoS2 composite for lithium ion battery anodes | |
Department | 清洁能源化学与材料实验室 |
Wan L(万柳)1; Sun W(孙伟)1,3; Shen JJ(申娟娟)1,2; Li XC(李小成)1; Li XC(李小成) | |
2016 | |
Source Publication | Electrochimica Acta |
ISSN | 0013-4686 |
Volume | 211Pages:962-971 |
Abstract | In this study, a facile MgO template-assisted route has been proposed for the preparation of carbon@MoS2 composites via a one-step hydrothermal method followed by a thermal annealing process. By using sucrose as a carbon source and commercial MgO powder as a structure-directing agent, a three-dimensional sphere-like carbon@MoS2 nanoarchitecture was assembled by one-dimensional worm-like nanorods which were composed of few-layered MoS2 nanosheets and amorphous carbon matrix. The influence of different amount of MgO template on the morphology, structure, and lithium storage performance of the carbon@MoS2 composites is systematically investigated. The carbon@MoS2-2 composite synthesized with a Mo precursor: MgO molar ratio of 1:1 exhibits much higher reversible capacity (905.3 mAh g−1 after 100 cycles at a current density of 100 mA g−1) and better high-rate capability (503.4 mAh g−1 at 5000 mA g−1) than those of bare MoS2 and template-free carbon@MoS2-0 composite. Impressively, superior cycling stability is achieved for the carbon@MoS2-2 composite with a capacity retention of 93.4% even after 400 charge/discharge cycles at 5000 mA g−1. The excellent electrochemical performance for carbon@MoS2-2 composite can be ascribed to its unique hierarchical nanoarchitecture and synergetic effect between MoS2 nanosheets and amorphous carbon. |
Keyword | Template-assisted Synthesis Molybdenum Disulfide Amorphous Carbon Lithium-ion Batteries |
Subject Area | 材料科学与物理化学 |
DOI | 10.1016/j.electacta.2016.06.115 |
Indexed By | SCI |
If | 4.798 |
Language | 英语 |
Funding Project | 新型电池材料研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20455 |
Collection | 清洁能源化学与材料实验室 |
Corresponding Author | Li XC(李小成) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China |
Recommended Citation GB/T 7714 | Wan L,Sun W,Shen JJ,et al. MgO-template-assisted synthesis of worm-like carbon@MoS2 composite for lithium ion battery anodes[J]. Electrochimica Acta,2016,211:962-971. |
APA | Wan L,Sun W,Shen JJ,Li XC,&李小成.(2016).MgO-template-assisted synthesis of worm-like carbon@MoS2 composite for lithium ion battery anodes.Electrochimica Acta,211,962-971. |
MLA | Wan L,et al."MgO-template-assisted synthesis of worm-like carbon@MoS2 composite for lithium ion battery anodes".Electrochimica Acta 211(2016):962-971. |
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1-s2.0-S001346861631(2767KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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