Improving catalytic activity and stability by in-situ regeneration of Ni-based catalyst for hydrogen production from ethanol steam reforming via controlling of active species dispersion | |
Department | OSSO国家重点实验室 |
Zhao XX(赵夏夏)1,2; Lu GX(吕功煊)1; Lv GX(吕功煊) | |
2016 | |
Source Publication | International Journal of Hydrogen Energy |
ISSN | 0360-3199 |
Volume | 41Issue:32Pages:13993-14002 |
Abstract | Nickel is an active component of catalyst for hydrogen production from ethanol steam reforming (ESR). However, Ni based catalyst usually meets severe deactivation due to coking. Normally, Ni catalyst regeneration could be achieved by heating coked catalyst in the oxygen contained atmosphere gas to remove coked carbon by oxidation of carbon. During this regeneration process, dispersed Ni particles are easily segregated because burning of carbon generates huge amount of heat and leads to uncontrollable temperature increase. In this paper, a new regeneration method of Ni catalyst was developed by re-deposition of another portion of Ni on deactivated Ni/SiO2 catalyst (denoted as catalyst 2) instead of O2 combustion of the deactivated catalyst (denoted as catalyst 1). H2-TPR results indicated that the metal-support interaction of catalyst 2 was stronger than that of catalyst 1, leading to higher metal dispersion and smaller Ni particles size over catalyst 2. The H2 chemisorption and HRTEM results indicated the dispersion of catalyst 2 reached 19.3%, much higher than 9.4% of catalyst 1. The dimension of late-loaded Ni particle was around 9.5 nm, even smaller than that of catalyst 1 (17.5 nm), corresponding to the high catalytic activity and stability of catalyst 2. The ethanol conversion of catalyst 1 and catalyst 2 were 76.5% and 94.6% at 500 °C, respectively. After short term of 20 h test, the ethanol conversion of catalyst 2 still remained, while that of the catalyst 1 decreased to about 40% of initial activity under same reaction condition (T = 550 °C, S/C = 7.5, LHSV = 4.1 h−1 and P = 1 atm.). |
Keyword | Regeneration Of Ni Catalyst Ethanol Steam Reforming Hydrogen Production Metal-support Interaction High Dispersion |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1016/j.ijhydene.2016.05.042 |
Funding Organization | the 973 Program and 863 Program of Department of Sciences and Technology China (Grant Nos. 2013CB632404;2012AA051501);the National Natural Science Foundation of China (Grant Nos. 21373245;21433007) |
Indexed By | SCI |
If | 3.582 |
Language | 英语 |
Funding Project | 环境催化与氢能源研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20353 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Lv GX(吕功煊) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Zhao XX,Lu GX,Lv GX. Improving catalytic activity and stability by in-situ regeneration of Ni-based catalyst for hydrogen production from ethanol steam reforming via controlling of active species dispersion[J]. International Journal of Hydrogen Energy,2016,41(32):13993-14002. |
APA | Zhao XX,Lu GX,&吕功煊.(2016).Improving catalytic activity and stability by in-situ regeneration of Ni-based catalyst for hydrogen production from ethanol steam reforming via controlling of active species dispersion.International Journal of Hydrogen Energy,41(32),13993-14002. |
MLA | Zhao XX,et al."Improving catalytic activity and stability by in-situ regeneration of Ni-based catalyst for hydrogen production from ethanol steam reforming via controlling of active species dispersion".International Journal of Hydrogen Energy 41.32(2016):13993-14002. |
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