| Pd/TiN nanocomposite catalysts for selective hydrogenation of phenol and its derivatives | |
| Department | OSSO国家重点实验室 |
Li HF(李海峰)1 ; Zhang QS(张勤生)1; Pang ZB(逄增波)1,2; Tian M(田密)1,2; Gao P(高平)3; Wang LL(王来来)1; Gao P(高平); Wang LL(王来来)
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| The second department | 固体润滑国家重点实验室 |
| 2016 | |
| Source Publication | Chinese Chemical Letters
 |
| ISSN | 1001-8417 |
| Volume | 27Issue:9Pages:1500-1504 |
| Abstract | Pd/TiN nanocomposite catalysts were fabricated for one-step selective hydrogenation of phenol to cyclohexanone successfully. High conversion of phenol (99%) and selectivity of cyclohexanone (98%) were obtained at 30 °C and 0.2 MPa H2 for 12 h in the mixed solvents of H2O and CH2Cl2. The Pd nanoparticles were stable in the reaction, and no aggregation was detected after four successive runs. The catalytic activity and selectivity depended on slightly the Pd particle sizes. The generality of the catalysts for this reaction was demonstrated by the selective hydrogenation of phenol derivatives, which showed that the catalyst was selective for the formation of cyclohexanone. |
| Keyword | Phenol Hydrogenation Cyclohexanone Tin Support Pd/tin Catalysts |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.cclet.2016.03.036 |
| Funding Organization | the National Natural Science Foundation of China (No. 21174155) |
| Indexed By | SCI |
| If | 1.932 |
| Language | 英语 |
| Funding Project | 有机功能材料研究组;空间润滑材料组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20346 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Gao P(高平); Wang LL(王来来) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Grad Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Li HF,Zhang QS,Pang ZB,et al. Pd/TiN nanocomposite catalysts for selective hydrogenation of phenol and its derivatives[J]. Chinese Chemical Letters,2016,27(9):1500-1504. |
| APA | Li HF.,Zhang QS.,Pang ZB.,Tian M.,Gao P.,...&王来来.(2016).Pd/TiN nanocomposite catalysts for selective hydrogenation of phenol and its derivatives.Chinese Chemical Letters,27(9),1500-1504. |
| MLA | Li HF,et al."Pd/TiN nanocomposite catalysts for selective hydrogenation of phenol and its derivatives".Chinese Chemical Letters 27.9(2016):1500-1504. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Pd_TiN nanocomposite（1457KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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