Lewis Acid Catalyzed Cyclization of Propargylic Alcohols with 2-Vinylphenol | |
Department | 固体润滑国家重点实验室 |
Han, Ya-Ping1; Song XR(宋贤荣)2; Qiu, Yi-Feng1; Li, Xue-Song1; Zhang, Heng-Rui1; Zhu, Xin-Yu1; Liu XY(刘雪原)1; Liang YM(梁永民)1,3; Liang YM(梁永民) | |
2016 | |
Source Publication | Organic Letters |
ISSN | 1523-7060 |
Volume | 18Issue:15Pages:3866-3869 |
Abstract | An unprecedented Lewis acid catalyzed, protection-free, and high-efficiency synthesis of valuable 3,4-dihydro-2H-2,4-methanochromans via cycloaddition of propargylic alkynols with 2-vinylphenol is described. This cycloaddition protocol, which tolerates a wide variety of functional groups, provides practical, versatile, and atom-economical access to a new class of appealing bridged-ring products in satisfactory yields. Compared with the reported reaction conditions for bridged-ring skeletons synthesis, the present reaction conditions are neutral, mild, and without any additives. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1021/acs.orglett.6b01875 |
Funding Organization | the National Science Foundation (NSF 21272101;21472073;21532001);the "111" Project, J1103307;Program for Changjiang Scholars and Innovative Research Team in University (IRT15R28);the Education Department of Jiangxi Province (GJJ150806) |
Indexed By | SCI |
If | 6.579 |
Language | 英语 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20316 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Liang YM(梁永民) |
Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Jiangxi Sci Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Han, Ya-Ping,Song XR,Qiu, Yi-Feng,et al. Lewis Acid Catalyzed Cyclization of Propargylic Alcohols with 2-Vinylphenol[J]. Organic Letters,2016,18(15):3866-3869. |
APA | Han, Ya-Ping.,Song XR.,Qiu, Yi-Feng.,Li, Xue-Song.,Zhang, Heng-Rui.,...&梁永民.(2016).Lewis Acid Catalyzed Cyclization of Propargylic Alcohols with 2-Vinylphenol.Organic Letters,18(15),3866-3869. |
MLA | Han, Ya-Ping,et al."Lewis Acid Catalyzed Cyclization of Propargylic Alcohols with 2-Vinylphenol".Organic Letters 18.15(2016):3866-3869. |
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