| Aerobic Oxidative Carbonylation of Enamides by Merging Palladium with Photoredox Catalysis | |
| Department | OSSO国家重点实验室 |
| Liu, Kun1; Zou, Minzhu1; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
| 2016 | |
| Source Publication | Journal of Organic Chemistry
 |
| ISSN | 0022-3263 |
| Volume | 81Issue:16Pages:7088-7092 |
| Abstract | Intramolecular oxidative carbonylation reaction is an efficient approach for constructing heterocycles. However, stoichiometric amount of hypervalent metal salts is usually required in this transformation. Here we show an aerobic intramolecular oxidative carbonylation of enamides by combining palladium and photoredox catalysis. The dual catalytic system enables oxygen directly as oxidant, which provides a mild and environmentally friendly method for the synthesis of 1,3-oxazin-6-ones. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/acs.joc.6b00965 |
| Funding Organization | the 973 Program (Grant 2012CB725302);the National Natural Science Foundation of China (Grants 21390400;21520102003;21272180;21302148);the Hubei Province Natural Science Foundation of China (Grant 2013CFA081);the Research Fund for the Doctoral Program of Higher Education of China (Grant 20120141130002);the Ministry of Science and Technology of China (Grant 2012YQ120060);the Program of Introducing Talents of Discipline to Universities of China (111 Program) |
| Indexed By | SCI |
| If | 4.849 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20312 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Lei AW(雷爱文) |
| Affiliation | 1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, Kun,Zou, Minzhu,Lei AW,et al. Aerobic Oxidative Carbonylation of Enamides by Merging Palladium with Photoredox Catalysis[J]. Journal of Organic Chemistry,2016,81(16):7088-7092. |
| APA | Liu, Kun,Zou, Minzhu,Lei AW,&雷爱文.(2016).Aerobic Oxidative Carbonylation of Enamides by Merging Palladium with Photoredox Catalysis.Journal of Organic Chemistry,81(16),7088-7092. |
| MLA | Liu, Kun,et al."Aerobic Oxidative Carbonylation of Enamides by Merging Palladium with Photoredox Catalysis".Journal of Organic Chemistry 81.16(2016):7088-7092. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| acs.joc.6b00965.pdf（714KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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