Effect of anion on micro/nano-tribological properties of ultra-thin imidazolium ionic liquid films on silicon wafer | |
Department | 固体润滑国家重点实验室 |
Zhao WJ(赵文杰); Zhu M(朱敏); Mo YF(莫宇飞); Bai MW(白明武) | |
2009 | |
Source Publication | Colloids and Surfaces A: Physicochemical and Engineering Aspects |
ISSN | 0927-7757 |
Volume | 332Pages:78-83 |
Abstract | Four kinds of room temperature ionic liquids (RTILs), as a new kind of lubricant for micro/nano- electromechanical system, with the same imidazolium cation but carrying different anions including hexafluorophosphate, tetrafluoroborate, nitrate and perchlorate were synthesized and these nano-scale films were prepared on single-crystal silicon wafer by dip-coating method. Atomic force microscopy was used to examine themorphologies of thefilms and evaluate their nano-friction and nano-adhesion proper- ties. Chemical compositions of the films were characterized with a multi-functional X-ray Photoelectron Spectrometer. Micro-tribological properties of RTIL films were evaluated using a ball-on-plate micro- tribometer, and compared to that of perfluoropolyether. Results showthat 3-butyl-1-methyl-imidazolium hexafluorophosphate exhibited the best anti-wear ability in comparisonwith the other four lubricants, so the ionic liquid films could be used as a kind of novel lubricant for application in MEMS/NEMS. Friction- reduction, adhesion resistance and anti-wear properties of RTILs were closely related to their anions. For the friction at nano-scale, the surface energy of the lubricant played a significant role,while the durability and friction-reduction of IL films strongly depend on their anions at micro-scale. |
Keyword | Micro/nano-friction Adhesion Ionic Liquids Ultra-thin FIlm Afm |
Subject Area | 材料科学与物理化学 |
Funding Organization | the National Natural Science Foundation of China (NSFC 50675217);National 973 Program (2007CB607601);Innovative Group Foundation (50421502) |
Indexed By | SCI |
Language | 英语 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/2030 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Bai MW(白明武) |
Recommended Citation GB/T 7714 | Zhao WJ,Zhu M,Mo YF,et al. Effect of anion on micro/nano-tribological properties of ultra-thin imidazolium ionic liquid films on silicon wafer[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2009,332:78-83. |
APA | 赵文杰,朱敏,莫宇飞,&白明武.(2009).Effect of anion on micro/nano-tribological properties of ultra-thin imidazolium ionic liquid films on silicon wafer.Colloids and Surfaces A: Physicochemical and Engineering Aspects,332,78-83. |
MLA | 赵文杰,et al."Effect of anion on micro/nano-tribological properties of ultra-thin imidazolium ionic liquid films on silicon wafer".Colloids and Surfaces A: Physicochemical and Engineering Aspects 332(2009):78-83. |
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