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Effects of additives on microstructure and properties of electrodeposited nanocrystalline Ni-Co alloy coatings of high cobalt content
Department固体润滑国家重点实验室
Ma, C.1; Wang, S. C.1; Low, C. T. J.2; Wang LP(王立平)3; F. C. Walsh2
2014
Source PublicationTransactions of the Institute of Metal Finishing
ISSN0020-2967
Volume92Issue:4Pages:189-195
AbstractSaccharin and 2-butin-1,4-diol (BD) were investigated as electrolyte additives to electrodeposit high quality nickel-cobalt alloys (78 +/- 2 at-%Co) as a protective surface coating on steel for tribological applications. The additives facilitated controlled electrodeposition of nanocrystalline coatings. The properties of the coatings investigated included surface morphology, grain size, crystalline texture and hardness. Tribological performance against a steel counterpart was studied via a reciprocating ball-on-disc apparatus. The coating microstrain could be manipulated from tensile to compressive and texture could be modified from (10 (1) over bar0) for hexagonal close packed (hcp) structure to (0002)(hcp)/(111) for face centred cubic (fcc) structure. The inhibition effect of absorbed species on electrodeposited nanocrystalline coatings is explained via analysis of grain size and texture. The coating from the bath with an optimised additive content had a high hardness (500 HV) due to its reduced grain size (11 +/- 1 nm) and improved tribological properties due to a high proportion of hcp structure.
KeywordAdditives Coating Ni-co Electrodeposition Nanocrystalline
Subject Area材料科学与物理化学
DOI10.1179/0020296713Z.000000000115
Funding OrganizationICUK
Indexed BySCI
If0.852
Language英语
Funding Project低维材料摩擦学组
compositor第三作者单位
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/20296
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorF. C. Walsh
Affiliation1.Univ Southampton, Natl Ctr Adv Tribol Southampton nCATS, Highfield SO17 1BJ, Hants, England
2.Univ Southampton, Electrochem Engn Lab, Highfield SO17 1BJ, Hants, England
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Ma, C.,Wang, S. C.,Low, C. T. J.,et al. Effects of additives on microstructure and properties of electrodeposited nanocrystalline Ni-Co alloy coatings of high cobalt content[J]. Transactions of the Institute of Metal Finishing,2014,92(4):189-195.
APA Ma, C.,Wang, S. C.,Low, C. T. J.,Wang LP,&F. C. Walsh.(2014).Effects of additives on microstructure and properties of electrodeposited nanocrystalline Ni-Co alloy coatings of high cobalt content.Transactions of the Institute of Metal Finishing,92(4),189-195.
MLA Ma, C.,et al."Effects of additives on microstructure and properties of electrodeposited nanocrystalline Ni-Co alloy coatings of high cobalt content".Transactions of the Institute of Metal Finishing 92.4(2014):189-195.
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