Effects of additives on microstructure and properties of electrodeposited nanocrystalline Ni-Co alloy coatings of high cobalt content | |
Department | 固体润滑国家重点实验室 |
Ma, C.1; Wang, S. C.1; Low, C. T. J.2; Wang LP(王立平)3; F. C. Walsh2 | |
2014 | |
Source Publication | Transactions of the Institute of Metal Finishing |
ISSN | 0020-2967 |
Volume | 92Issue:4Pages:189-195 |
Abstract | Saccharin and 2-butin-1,4-diol (BD) were investigated as electrolyte additives to electrodeposit high quality nickel-cobalt alloys (78 +/- 2 at-%Co) as a protective surface coating on steel for tribological applications. The additives facilitated controlled electrodeposition of nanocrystalline coatings. The properties of the coatings investigated included surface morphology, grain size, crystalline texture and hardness. Tribological performance against a steel counterpart was studied via a reciprocating ball-on-disc apparatus. The coating microstrain could be manipulated from tensile to compressive and texture could be modified from (10 (1) over bar0) for hexagonal close packed (hcp) structure to (0002)(hcp)/(111) for face centred cubic (fcc) structure. The inhibition effect of absorbed species on electrodeposited nanocrystalline coatings is explained via analysis of grain size and texture. The coating from the bath with an optimised additive content had a high hardness (500 HV) due to its reduced grain size (11 +/- 1 nm) and improved tribological properties due to a high proportion of hcp structure. |
Keyword | Additives Coating Ni-co Electrodeposition Nanocrystalline |
Subject Area | 材料科学与物理化学 |
DOI | 10.1179/0020296713Z.000000000115 |
Funding Organization | ICUK |
Indexed By | SCI |
If | 0.852 |
Language | 英语 |
Funding Project | 低维材料摩擦学组 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20296 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | F. C. Walsh |
Affiliation | 1.Univ Southampton, Natl Ctr Adv Tribol Southampton nCATS, Highfield SO17 1BJ, Hants, England 2.Univ Southampton, Electrochem Engn Lab, Highfield SO17 1BJ, Hants, England 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Ma, C.,Wang, S. C.,Low, C. T. J.,et al. Effects of additives on microstructure and properties of electrodeposited nanocrystalline Ni-Co alloy coatings of high cobalt content[J]. Transactions of the Institute of Metal Finishing,2014,92(4):189-195. |
APA | Ma, C.,Wang, S. C.,Low, C. T. J.,Wang LP,&F. C. Walsh.(2014).Effects of additives on microstructure and properties of electrodeposited nanocrystalline Ni-Co alloy coatings of high cobalt content.Transactions of the Institute of Metal Finishing,92(4),189-195. |
MLA | Ma, C.,et al."Effects of additives on microstructure and properties of electrodeposited nanocrystalline Ni-Co alloy coatings of high cobalt content".Transactions of the Institute of Metal Finishing 92.4(2014):189-195. |
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LZ01029287.pdf(1264KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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