| Catalytic performance of TiO2@Ag composites prepared by modified photodeposition method | |
| Department | 固体润滑国家重点实验室 |
| Ma, Jianqi1,2,3; Guo, Xiaohua1; Zhang, Yanyan3; Ge, Hongguang1 | |
| 2014 | |
| Source Publication | Chemical Engineering Journal
 |
| ISSN | 1385-8947 |
| Volume | 258Pages:247-253 |
| Abstract | In this work, monodispersed TiO2 spheres with diameter of about 360 nm were prepared by an acetic acid assisted sol–gel method. Core–shell structure TiO2@Ag composites, constructed by the anatase TiO2 sphere cores and Ag nanoparticles (NPs) shell, were obtained via Ag nanoseed mediated photochemical reduction (modified photo-deposition) and characterized using transmission electron microscopy, XRD, X-ray photoelectron spectroscope and UV–vis spectroscopy. The characterization results indicate that Ag NPs with an average size of about 10 nm are uniformly distributed on the surface of the Ag nanoseed modified TiO2 spheres under UV radiation. For the purpose of comparison, the TiO2/Ag composites were also prepared by conventional photodeposition method and characterized. The catalytic performance of the as-prepared composites through different photo-deposited methods was evaluated by catalysis reduction of 4-nitrophenol. The results indicated that the catalytic efficiency of TiO2@Ag core–shell structures is higher than that of TiO2/Ag composites. This could be because TiO2@Ag composites have a more homogeneous distribution of Ag NPs on the TiO2 surface as well as a better contact between the Ag NPs and TiO2 than TiO2/Ag composites. |
| Keyword | Tio2 Spheres Modified Photo-deposition Tio2@ag Composites Catalytic Performance |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1016/j.cej.2014.06.120 |
| Funding Organization | the National Natural Science Foundation of China (No. 21373132);Natural Science Foundation of Shannxi Province of China (No. 2010JM2016) |
| Indexed By | SCI |
| If | 4.321 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20293 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Ma, Jianqi |
| Affiliation | 1.Shaanxi Univ Technol, Sch Chem & Environm Sci, Hanzhong 723001, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 3.Shaanxi Univ Technol, Sch Biol Sci & Engn, Hanzhong 723001, Peoples R China |
| Recommended Citation GB/T 7714 | Ma, Jianqi,Guo, Xiaohua,Zhang, Yanyan,et al. Catalytic performance of TiO2@Ag composites prepared by modified photodeposition method[J]. Chemical Engineering Journal,2014,258:247-253. |
| APA | Ma, Jianqi,Guo, Xiaohua,Zhang, Yanyan,&Ge, Hongguang.(2014).Catalytic performance of TiO2@Ag composites prepared by modified photodeposition method.Chemical Engineering Journal,258,247-253. |
| MLA | Ma, Jianqi,et al."Catalytic performance of TiO2@Ag composites prepared by modified photodeposition method".Chemical Engineering Journal 258(2014):247-253. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 1-s2.0-S138589471400（1775KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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