| A novel octadecylsilane functionalized graphene oxide/silica composite stationary phase for high performance liquid chromatography | |
| Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Liang XJ(梁晓静) ; Wang S(王帅); Liu SJ(刘淑娟); Liu X(刘霞); Jiang SX(蒋生祥); Jiang SX(蒋生祥)
| |
| 2012 | |
| Source Publication | Journal of Separation Science
 |
| ISSN | 1615-9306 |
| Volume | 35Issue:16Pages:2003-2009 |
| Abstract | An octadecylsilane functionalized graphene oxide/silica stationary phase was fabricated by assembling graphene oxide onto the silica particles through an amide bond and subsequent immobilization of octadecylsilane. The chromatographic properties of the stationary phase were investigated by reversed-phase chromatography with alkylbenzenes, polycyclic aromatic hydrocarbons, amines, and phenolic compounds as the analytes. All the compounds achieved good separation on the column. The comparison between a C18 commercial column and the new stationary phase indicated that the existence of π-electron system of graphene oxide allows π-π interaction between analyte and octadecylsilane functionalized graphene oxide/silica stationary phase except for hydrophobic interaction, while only hydrophobic interaction presented between analyte and C18 commercial column. This suggests that some analytes can be better separated on the octadecylsilane functionalized graphene oxide/silica column. |
| Keyword | Graphene Oxide Hydrophobic Interaction P-p Interaction Octadecylsilane Functionalized Graphene Oxide Silica Stationary Phase |
| Subject Area | 分析化学与药物化学 |
| DOI | 10.1002/jssc.201200258 |
| Funding Organization | the National Natural Science Foundation of China (21105107;20905072) |
| Indexed By | SCI |
| If | 2.591 |
| Language | 英语 |
| Funding Project | 药物分离材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20253 |
| Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
| Corresponding Author | Jiang SX(蒋生祥) |
| Affiliation | Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China |
| Recommended Citation GB/T 7714 | Liang XJ,Wang S,Liu SJ,et al. A novel octadecylsilane functionalized graphene oxide/silica composite stationary phase for high performance liquid chromatography[J]. Journal of Separation Science,2012,35(16):2003-2009. |
| APA | Liang XJ,Wang S,Liu SJ,Liu X,Jiang SX,&蒋生祥.(2012).A novel octadecylsilane functionalized graphene oxide/silica composite stationary phase for high performance liquid chromatography.Journal of Separation Science,35(16),2003-2009. |
| MLA | Liang XJ,et al."A novel octadecylsilane functionalized graphene oxide/silica composite stationary phase for high performance liquid chromatography".Journal of Separation Science 35.16(2012):2003-2009. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Liang_et_al-2012-Jou（752KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment