| Palladium-catalyzed Si-C bond-forming silylation of aryl iodides with hydrosilanes: an enhanced enantioselective synthesis of silicon-stereogenic silanes by desymmetrization | |
| Department | OSSO国家重点实验室 |
| Chen, Li1; Huang, Jiang-Bo1; Xu, Zheng1; Zheng ZJ(郑战江)1; Yang KF(杨科芳)1; Cui, Yu-Ming1; Cao, Jian1; Xu LW(徐利文)1,2; Yang KF(杨科芳); Xu LW(徐利文) | |
| 2016 | |
| Source Publication | RSC Advances
 |
| ISSN | 2046-2069 |
| Volume | 6Issue:71Pages:67113-67117 |
| Abstract | An enantioselective Pd-catalyzed silicon–carbon bond-forming silylation reaction of aryl iodides with hydrosilanes for the synthesis of silicon-stereogenic silanes has been developed, in which a systematic optimization of a TADDOL-derived monodentate phosphoramidite ligand set resulted in the identification of a new TADDOL-derived phosphoramidite ligand that accesses chiral silanes with moderate to good yield and enantioselectivity under mild conditions. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c6ra12873d |
| Funding Organization | the National Natural Science Foundation of China (51303043;21472031;21503060);Zhejiang Provincial Natural Science Foundation of China (LR14B030001;LY14B020013);Science and Technology Department of Zhejiang Province (2015C31138);Hangzhou Science and Technology Bureau of China (20140432B04) |
| Indexed By | SCI |
| If | 3.108 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20247 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Yang KF(杨科芳); Xu LW(徐利文) |
| Affiliation | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 311121, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou, Peoples R China |
| Recommended Citation GB/T 7714 | Chen, Li,Huang, Jiang-Bo,Xu, Zheng,et al. Palladium-catalyzed Si-C bond-forming silylation of aryl iodides with hydrosilanes: an enhanced enantioselective synthesis of silicon-stereogenic silanes by desymmetrization[J]. RSC Advances,2016,6(71):67113-67117. |
| APA | Chen, Li.,Huang, Jiang-Bo.,Xu, Zheng.,Zheng ZJ.,Yang KF.,...&徐利文.(2016).Palladium-catalyzed Si-C bond-forming silylation of aryl iodides with hydrosilanes: an enhanced enantioselective synthesis of silicon-stereogenic silanes by desymmetrization.RSC Advances,6(71),67113-67117. |
| MLA | Chen, Li,et al."Palladium-catalyzed Si-C bond-forming silylation of aryl iodides with hydrosilanes: an enhanced enantioselective synthesis of silicon-stereogenic silanes by desymmetrization".RSC Advances 6.71(2016):67113-67117. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c6ra12873d.pdf（707KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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