CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3 | |
Department | 绿色化学研究发展中心 |
Shang JP(尚建鹏)1; Guo, Xiaoguang2; Li, Zuopeng1; Deng YQ(邓友全)3; Shang JP(尚建鹏) | |
2016 | |
Source Publication | Green Chemistry |
ISSN | 1463-9262 |
Volume | 18Issue:10Pages:3082-3088 |
Abstract | This paper reports an effective route for the syntheses of hydroxy carbamates from the reaction of CO2, epoxides and amines catalyzed by a Au/Fe2O3 catalyst. Under the optimized reaction conditions, various hydroxy carbamates were successfully synthesized with 92–98% isolated yields. The catalyst could be reused for several runs without deactivation. A plausible reaction mechanism was proposed by which the hydroxy carbamate was formed through an ammonium carbamate intermediate and the catalyst mainly promoted further nucleophilic addition between the epoxide and ammonium carbamate. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c5gc02772a |
Funding Organization | the Doctoral Scientific Research Foundation of Shanxi Datong University (2012-B-12);Basic Research Programs of Science and Technology Department of Datong (2015107);National Natural Science Foundation of China (no: 21473185;U1532117) |
Indexed By | SCI |
If | 9.125 |
Language | 英语 |
Funding Project | 绿色催化课题组 |
compositor | 第三作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20101 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Shang JP(尚建鹏) |
Affiliation | 1.Shanxi Datong Univ, Dept Chem & Environm Engn, Datong 037009, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Shang JP,Guo, Xiaoguang,Li, Zuopeng,et al. CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3[J]. Green Chemistry,2016,18(10):3082-3088. |
APA | Shang JP,Guo, Xiaoguang,Li, Zuopeng,Deng YQ,&尚建鹏.(2016).CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3.Green Chemistry,18(10),3082-3088. |
MLA | Shang JP,et al."CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3".Green Chemistry 18.10(2016):3082-3088. |
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c5gc02772a.pdf(1115KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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