| Amide exchange reaction: a simple and efficient CuO catalyst for diacetamide synthesis | |
| Department | OSSO国家重点实验室 |
Li QH(李庆贺)1,2; Wang PX(王培学)1 ; Deng YQ(邓友全)1; Deng YQ(邓友全)
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| The second department | 固体润滑国家重点实验室 |
| 2016 | |
| Source Publication | RSC Advances
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| ISSN | 2046-2069 |
| Volume | 6Issue:47Pages:40890-40894 |
| Abstract | A highly copper-catalysed amide exchange reaction of hexamethylenediamine (HDA) with CH3CN and H2O for the synthesis of hexamethylenebisacetamide (HMBA) without an organic solvent or gas protection was developed. 100% HDA conversion and >99% HMBA selectivity was obtained. X-ray diffraction, scanning emission microscopy, and temperature-programmed reduction of hydrogen were used to characterize the structural properties of the catalyst. The reaction mechanism was also investigated. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c6ra05563j |
| Funding Organization | the National Natural Science Foundation of China (No. 21173240) |
| Indexed By | SCI |
| If | 3.108 |
| Language | 英语 |
| Funding Project | 绿色催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20077 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Deng YQ(邓友全) |
| Affiliation | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China 2.Graduate University of Chinese Academy of Sciences, Beijing 100049, China |
| Recommended Citation GB/T 7714 | Li QH,Wang PX,Deng YQ,et al. Amide exchange reaction: a simple and efficient CuO catalyst for diacetamide synthesis[J]. RSC Advances,2016,6(47):40890-40894. |
| APA | Li QH,Wang PX,Deng YQ,&邓友全.(2016).Amide exchange reaction: a simple and efficient CuO catalyst for diacetamide synthesis.RSC Advances,6(47),40890-40894. |
| MLA | Li QH,et al."Amide exchange reaction: a simple and efficient CuO catalyst for diacetamide synthesis".RSC Advances 6.47(2016):40890-40894. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c6ra05563j.pdf（598KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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