Naphthalene-Functionalized, Photoluminescent Room Temperature Ionic Liquids Bearing Small Counterions | |
Department | 清洁能源化学与材料实验室 |
Zhu, Hongxia1; Zhang, Geping1; Chen, Mengjun1; Zhou SJ(周升菊)2; Li, Guihua1; Wang, Xiaolin1; Zhu, Qingzeng1; Li HG(李洪光)2; Hao JC(郝京诚)1; Li HG(李洪光); Hao JC(郝京诚) | |
2016 | |
Source Publication | Chemistry - A European Journal |
ISSN | 0947-6539 |
Volume | 22Issue:18Pages:6286-6293 |
Abstract | Obtaining π-conjugated room temperature ionic liquids (RTILs) is difficult because of the relatively strong π–π interaction among the π-moieties. Existing strategies by using bulky counterions greatly hindered further property optimization and potential applications of these intriguing functional fluids through simple ion exchange. Herein, four naphthalene-functionalized, π-conjugated RTILs with small counterions (Br−) have been facilely synthesized with high yields. Our strategy is to attach branched alkyl chains to the cationic backbone of the target compounds (2 a–d), which effectively tune inter- and intramolecular interactions. Compounds 2 a–d have satisfactory thermal stability (up to 300 °C) and low melting points (<−19 °C). Rheological measurements revealed the fluid character of 2 a–d, whose viscosity decrease with the increase of the alkyl chain length and temperature. The presence of the π-conjugated naphthalene moiety imparts 2 a–d photoluminescent properties in bulk solutions. Moreover, the absence of strong π–π stacking among the naphthalene units in solvent-free states enables them to be used as a new generation of photoluminescent inks. |
Keyword | Branched Alkyl Chains Imidazole Ionic Liquids Naphthalene Photoluminescence |
Subject Area | 材料科学与物理化学 |
DOI | 10.1002/chem.201504764 |
Funding Organization | the National Natural Science Foundation of China (Nos. 61474124;21402215; 21420102006);the Hundred Talents Program of Chinese Academy of Sciences (Y20245YBR1) |
Indexed By | SCI |
If | 5.317 |
Language | 英语 |
Funding Project | 柔性有机太阳能电池研究组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20058 |
Collection | 清洁能源化学与材料实验室 固体润滑国家重点实验室(LSL) |
Corresponding Author | Li HG(李洪光); Hao JC(郝京诚) |
Affiliation | 1.Key Laboratory of Colloid and Interface Chemistry & Key Laboratory of Special Aggregated Materials, Ministry of Education Shandong University, Jinan, 250100, Shandong Province (China) 2.State Key Laboratory of Solid Lubrication & Laboratory of Clean Energy Chemistry and Materials Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences Lanzhou, 730000, Gansu Province (China) |
Recommended Citation GB/T 7714 | Zhu, Hongxia,Zhang, Geping,Chen, Mengjun,et al. Naphthalene-Functionalized, Photoluminescent Room Temperature Ionic Liquids Bearing Small Counterions[J]. Chemistry - A European Journal,2016,22(18):6286-6293. |
APA | Zhu, Hongxia.,Zhang, Geping.,Chen, Mengjun.,Zhou SJ.,Li, Guihua.,...&郝京诚.(2016).Naphthalene-Functionalized, Photoluminescent Room Temperature Ionic Liquids Bearing Small Counterions.Chemistry - A European Journal,22(18),6286-6293. |
MLA | Zhu, Hongxia,et al."Naphthalene-Functionalized, Photoluminescent Room Temperature Ionic Liquids Bearing Small Counterions".Chemistry - A European Journal 22.18(2016):6286-6293. |
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