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Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgitesuperabsorbentcomposites
Department环境材料与生态化学研究发展中心
Zhang JP(张俊平); Wang Q(汪琴); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn
2007
Source PublicationCarbohydrate Polymers
ISSN0144-8617
Volume68Issue:2Pages:367-374
AbstractA novel chitosan-g-poly(acrylic acid)/attapulgitesuperabsorbentcomposite with water absorbency of 159.6 g g?1 in distilled water and 42.3 g g?1 in 0.9 wt% NaCl solution was prepared by graft polymerization with chitosan, acrylic acid and attapulgite in aqueous solution, using N,N′-methylenebisacrylamide as a crosslinker and ammonium persulfate as an initiator. Factors influencing water absorbency of the superabsorbentcomposite were investigated, such as average molecular weight of chitosan, weight ratio of acrylic acid to chitosan, dewatering method, the amount of crosslinker and attapulgite. The result from FTIR spectra showed that –OH of attapulgite, –OH, –NHCO and –NH2 of chitosan participated in graft polymerization with acrylic acid. The introduced attapulgite enhanced thermal stability of the chitosan-g-poly(acrylic acid) superabsorbent and formed a loose and more porous surface. Introducing a small amount of attapulgite also enhanced water absorbency of the chitosan-g-poly(acrylic acid) superabsorbent.
KeywordSuperabsorbentcomposite Water Absorbency Attapulgite Chitosan
Subject Area功能高分子
Funding Organization科技部863重大专项子课题(2005AA2Z4030);甘肃省科技攻关项目(2GS052-A52-002-07)
Indexed BySCI
Language英语
Funding Project功能复合材料组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/199
Collection环境材料与生态化学研究发展中心
Corresponding Author王爱勤 aqwang@licp.cas.cn
Recommended Citation
GB/T 7714
Zhang JP,Wang Q,Wang AQ,et al. Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgitesuperabsorbentcomposites[J]. Carbohydrate Polymers,2007,68(2):367-374.
APA 张俊平,汪琴,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2007).Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgitesuperabsorbentcomposites.Carbohydrate Polymers,68(2),367-374.
MLA 张俊平,et al."Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgitesuperabsorbentcomposites".Carbohydrate Polymers 68.2(2007):367-374.
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