Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics

doi:10.1007/s10562-016-1750-5

	Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics
Department	OSSO国家重点实验室
	Song HY(宋河远)1,2 ; Jin FX(金福祥)1 ; Jin RH(靳荣华)1 ; Kang MR(康美荣)1 ; Li Z(李臻)1 ; Chen J(陈静)1 ; Li Z(李臻); Chen J(陈静)
	2016
Source Publication	Catalysis Letters
ISSN	1011-372X
Volume	146 Issue:7 Pages:1264-1272
Abstract	Methylation of formaldehyde with various aromatics under functional ionic liquids catalysis has been developed. Among the ionic liquids investigated, triphenyl-(4-sulfobutyl)-phosphonium triflate ([TTPBs][CF₃SO₃]) showed high activity and afforded excellent yields of diarylmethane derivatives. A mechanism for the catalytic performance of [TTPBs][CF₃SO₃] is proposed. Besides, the catalyst can simply be separated from the reaction mixture by centrifugation and be recycled ten times without noticeable loss of activity.
Keyword	Formaldehyde Methylation Diarylmethane Ionic Liquids
Subject Area	物理化学与绿色催化
DOI	10.1007/s10562-016-1750-5
Funding Organization	the National Natural Science Foundation of China (Project No. 21473225;21133011)
Indexed By	SCI
If	2.799
Language	英语
Funding Project	分子催化与技术课题组
compositor	第一作者单位
Citation statistics	Cited Times:6[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/19806
Collection	羰基合成与选择氧化国家重点实验室（OSSO）
Corresponding Author	Li Z(李臻); Chen J(陈静)
Affiliation	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation GB/T 7714	Song HY,Jin FX,Jin RH,et al. Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics[J]. Catalysis Letters,2016,146(7):1264-1272.
APA	Song HY.,Jin FX.,Jin RH.,Kang MR.,Li Z.,...&陈静.(2016).Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics.Catalysis Letters,146(7),1264-1272.
MLA	Song HY,et al."Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics".Catalysis Letters 146.7(2016):1264-1272.

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