LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes
DepartmentOSSO国家重点实验室
Cao RW(曹汝伟)1,2; Zhang JL(张金龙)1; Zhou H(周慧)1,2; Yang HM(杨化萌)1; Jiang GX(蒋高喜)1,3; Jiang GX(蒋高喜)
2016
Source PublicationOrganic & Biomolecular Chemistry
ISSN1477-0520
Volume14Issue:7Pages:2191-2194
Abstract

A highly atom-economical allylation of oxindoles with vinyl cyclopropanes catalyzed by Pd(PPh3)4 has been developed, setting up a practical venue for the installation of an all-carbon quaternary center at the 3-position in oxindoles under mild reaction conditions. Importantly, the reaction proceeded well without any additives and no waste was produced, affording linear products with high regioselectivities (>20 : 1). Enantioselective allylic alkylation has also been realized to provide the desired products in good yields and 35% ee.

Subject Area物理化学与绿色催化
DOI10.1039/c5ob02653a
Funding Organizationthe Hundred Talent Program of Chinese Academy of Sciences (CAS);the National Natural Science Foundation of China (21202175)
Indexed BySCI
If3.564
Language英语
compositor第一作者单位
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/19751
Collection羰基合成与选择氧化国家重点实验室(OSSO)
苏州研究院
Corresponding AuthorJiang GX(蒋高喜)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Div Adv Nanomat, Suzhou 215123, Peoples R China
Recommended Citation
GB/T 7714
Cao RW,Zhang JL,Zhou H,et al. Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes[J]. Organic & Biomolecular Chemistry,2016,14(7):2191-2194.
APA Cao RW,Zhang JL,Zhou H,Yang HM,Jiang GX,&蒋高喜.(2016).Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes.Organic & Biomolecular Chemistry,14(7),2191-2194.
MLA Cao RW,et al."Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes".Organic & Biomolecular Chemistry 14.7(2016):2191-2194.
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