Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes | |
Department | OSSO国家重点实验室 |
Cao RW(曹汝伟)1,2; Zhang JL(张金龙)1; Zhou H(周慧)1,2; Yang HM(杨化萌)1; Jiang GX(蒋高喜)1,3; Jiang GX(蒋高喜) | |
2016 | |
Source Publication | Organic & Biomolecular Chemistry |
ISSN | 1477-0520 |
Volume | 14Issue:7Pages:2191-2194 |
Abstract | A highly atom-economical allylation of oxindoles with vinyl cyclopropanes catalyzed by Pd(PPh3)4 has been developed, setting up a practical venue for the installation of an all-carbon quaternary center at the 3-position in oxindoles under mild reaction conditions. Importantly, the reaction proceeded well without any additives and no waste was produced, affording linear products with high regioselectivities (>20:1). Enantioselective allylic alkylation has also been realized to provide the desired products in good yields and 35% ee. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c5ob02653a |
Funding Organization | the Hundred Talent Program of Chinese Academy of Sciences (CAS);the National Natural Science Foundation of China (21202175) |
Indexed By | SCI |
If | 3.564 |
Language | 英语 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19751 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) 苏州研究院 |
Corresponding Author | Jiang GX(蒋高喜) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Div Adv Nanomat, Suzhou 215123, Peoples R China |
Recommended Citation GB/T 7714 | Cao RW,Zhang JL,Zhou H,et al. Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes[J]. Organic & Biomolecular Chemistry,2016,14(7):2191-2194. |
APA | Cao RW,Zhang JL,Zhou H,Yang HM,Jiang GX,&蒋高喜.(2016).Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes.Organic & Biomolecular Chemistry,14(7),2191-2194. |
MLA | Cao RW,et al."Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes".Organic & Biomolecular Chemistry 14.7(2016):2191-2194. |
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c5ob02653a.pdf(406KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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