| Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Peng XG(彭新高); Wang Z(王铮); Xia CG(夏春谷) ; Ding KL(丁奎岭)
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| 2008 | |
| Source Publication | Tetrahedron Letters
 |
| ISSN | 0040-4039 |
| Volume | 49Pages:4862-4864 |
| Abstract | A new class of chiral modular bidentate phosphonite ligands has been synthesized in good overall yields by using cheap trans-1,2-diaminocyclohexane and ferrocene as starting materials, and applied in the Rh(I)-catalyzed asymmetric hydroformylation of vinyl acetate and styrene to afford the corresponding optically active aldehydes with good regioselectivity (up to 16.9 b/l ratio) and moderate to good enantioselectivity (up to 83% ee). The substituents on the backbone of the ligands are found to exhibit a remarkable effect on both the regio- and enantioselectivity of the catalysis. |
| Keyword | Asymmetric Catalysis Hydroformylation Bidentate Ligand Phosphonite Rhodium |
| Subject Area | 清洁催化与生物转化 |
| Funding Organization | the National Natural Science Foundation of China (Nos. 20532050;20423001);the Chinese Academy of Sciences;the Major Basic Research Development Program of China (Grant No. 2006CB806106) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 清洁催化与生物转化研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1967 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷); Ding KL(丁奎岭) |
| Recommended Citation GB/T 7714 | Peng XG,Wang Z,Xia CG,et al. Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation[J]. Tetrahedron Letters,2008,49:4862-4864. |
| APA | 彭新高,王铮,夏春谷,&丁奎岭.(2008).Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation.Tetrahedron Letters,49,4862-4864. |
| MLA | 彭新高,et al."Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation".Tetrahedron Letters 49(2008):4862-4864. |
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| 38_Tetrahedron Lett.（162KB） | 开放获取 | License | View Application Full Text | |||
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