A Pd(OAc)2/[mmim]I catalyst system for oxidative carbonylation of amines to carbamates, ureas, and 2-oxazolidinones

	A Pd(OAc)2/[mmim]I catalyst system for oxidative carbonylation of amines to carbamates, ureas, and 2-oxazolidinones
Department	羰基合成与选择氧化国家重点实验室
	Peng XG(彭新高); Li FW(李福伟); Hu XX(胡霄雪); Xia CG(夏春谷); C.A. Sandoval
	2008
Source Publication	Chinese J. Catal.
ISSN	0253-9837
Volume	29 Issue:7 Pages:638-642
Abstract	A Pd(OAc)2/[mmim]I ([mmim]I=1-methyl-3-methylimidazolium iodide) catalyst system was applied to the oxidative carbonylation of aliphatic amines, aromatic amines, and amino alcohols to carbamates, ureas, and 2-oxazolidinones under different conditions. The catalytic turnover frequencies (TOF, moles of amines converted per mole of catalyst per hour) were 12417, 17368, and 4114 h−1 for the production of methyl N-phenyl carbamate, N,N′-diphenyl urea, and 2-benzoxazolinone, respectively.
Keyword	Palladium Ionic Liquid Amine Oxidative Carbonylation Carbamate Urea 2-oxazolidinone
Subject Area	清洁催化与生物转化
Funding Organization	the National Natural Science Foundation of China (20533080;20625308)
Indexed By	SCI ; CSCD
Language	英语
Funding Project	清洁催化与生物转化研究组 ; 管理与大型仪器组
Citation statistics	Cited Times:4[CSCD] [CSCD Record]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/1962
Collection	羰基合成与选择氧化国家重点实验室（OSSO）
Corresponding Author	Xia CG(夏春谷)
Recommended Citation GB/T 7714	Peng XG,Li FW,Hu XX,et al. A Pd(OAc)2/[mmim]I catalyst system for oxidative carbonylation of amines to carbamates, ureas, and 2-oxazolidinones[J]. Chinese J. Catal.,2008,29(7):638-642.
APA	彭新高,李福伟,胡霄雪,夏春谷,&C.A. Sandoval.(2008).A Pd(OAc)2/[mmim]I catalyst system for oxidative carbonylation of amines to carbamates, ureas, and 2-oxazolidinones.Chinese J. Catal.,29(7),638-642.
MLA	彭新高,et al."A Pd(OAc)2/[mmim]I catalyst system for oxidative carbonylation of amines to carbamates, ureas, and 2-oxazolidinones".Chinese J. Catal. 29.7(2008):638-642.

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