| Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}] | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Yang JM(杨晶沐); Hu B(胡斌) ; Ge J(葛进); Xia CG(夏春谷)
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| 2008 | |
| Source Publication | JOURNAL OF CHEMICAL RESEARCH
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| ISSN | 0308-2342 |
| Pages | 322-323 |
| Abstract | Reaction of Ru3(CO)12 with the thio-Schiff base ligand acetylferrocenyl-thiosemicarbazone provides a one-step synthesis of the chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}] as a racemic mixture. One molecule of thiosemicarbazone was consumed in the cluster formation process, in which the ligand was deprotonated and acted as a bidentate N, S donor as well as bridging. The title cluster has been characterised by NMR, IR, HPLC and an X-ray structure determination. |
| Keyword | Homometallic Chiral Cluster Enantioseparation Acetylferrocenyl-thiosemicarbazone X-ray Structure |
| Subject Area | 清洁催化与生物转化 |
| Funding Organization | the National Science Fund for Distinguished Young Scholars of China (No. 20625308) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 清洁催化与生物转化研究组 ; 羰基金属功能材料研究组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1961 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷) |
| Recommended Citation GB/T 7714 | Yang JM,Hu B,Ge J,et al. Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}][J]. JOURNAL OF CHEMICAL RESEARCH,2008:322-323. |
| APA | 杨晶沐,胡斌,葛进,&夏春谷.(2008).Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}].JOURNAL OF CHEMICAL RESEARCH,322-323. |
| MLA | 杨晶沐,et al."Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}]".JOURNAL OF CHEMICAL RESEARCH (2008):322-323. |
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