Electrooxidation behavior and electrochemistry determination method of the xanthophylls: Lutein in nonaqueous media | |
Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Yue Y(岳莹)1,2,3; Liang Q(梁卿)1,2; Liao Y(廖原)1,2; Guo Y(郭勇)1,2; Shao SJ(邵士俊)1,2; Shao SJ(邵士俊) | |
2012 | |
Source Publication | Journal of Electroanalytical Chemistry |
ISSN | 1572-6657 |
Volume | 682Pages:90-94 |
Abstract | The electrooxidation behavior and determination of lutein, which is an important botanical pigment and antioxidant, were investigated by electrochemical method in nonaqueous media for the first time. The electrooxidation of lutein is a diffusion-controlled irreversible reaction. The electrochemical method shows some selectivity for lutein and lutein esters due to their different end structures, and can be applied to discrimination and qualitative detection of the two, which cannot be achieved by the spectrophotometry. Besides, using differential pulse voltammetry, anodic currents of lutein are linear with their concentration in the range of 0.5–76 μM, with detection limits of 0.1 μM. The proposed determination method has been successfully applied in the real sample analysis with good sensitivity and reproducibility, confirming it should be a useful addition to the analytical methodology available for monitoring the concentrates of lutein. |
Keyword | Lutein Carotenoids Glass Carbon Electrode Electrochemical Determination |
Subject Area | 分析化学与药物化学 |
DOI | 10.1016/j.jelechem.2012.07.029 |
Funding Organization | the Western Action Project of Chinese Academy of Sciences (KGCX2-YW-510) |
Indexed By | SCI |
If | 2.672 |
Language | 英语 |
Funding Project | 药物分子识别研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19561 |
Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Corresponding Author | Shao SJ(邵士俊) |
Affiliation | 1.Chinese Acad Sci, Key Lab Chem NW Plant Resources, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Key Lab Nat Med Gansu Prov, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
Recommended Citation GB/T 7714 | Yue Y,Liang Q,Liao Y,et al. Electrooxidation behavior and electrochemistry determination method of the xanthophylls: Lutein in nonaqueous media[J]. Journal of Electroanalytical Chemistry,2012,682:90-94. |
APA | Yue Y,Liang Q,Liao Y,Guo Y,Shao SJ,&邵士俊.(2012).Electrooxidation behavior and electrochemistry determination method of the xanthophylls: Lutein in nonaqueous media.Journal of Electroanalytical Chemistry,682,90-94. |
MLA | Yue Y,et al."Electrooxidation behavior and electrochemistry determination method of the xanthophylls: Lutein in nonaqueous media".Journal of Electroanalytical Chemistry 682(2012):90-94. |
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