| Divergent Synthesis of Benzene Derivatives: Bronsted Acid Catalyzed and Iodine-Promoted Tandem Cyclization of 5,2-Enyn-1-ones | |
| Department | 固体润滑国家重点实验室 |
| Yang F(杨芳)1; Qiu, Yi-Feng1; Ji KG(纪克攻)1; Niu YN(牛雁宁)1; Ali, Shaukat1; Liang YM(梁永民)1,2; Liang YM(梁永民) | |
| 2012 | |
| Source Publication | Journal of Organic Chemistry
 |
| ISSN | 0022-3263 |
| Volume | 77Issue:20Pages:9029-9037 |
| Abstract | Highly substituted benzene derivatives, including alkoxy-, iodoalkoxy-, and diiodo-substituted benzenes, can be selectively synthesized via Brønsted acid catalyzed and iodine-promoted tandem carbocyclization respectively. This reaction involved a direct process for C–C bond formation from 5,2-enyn-1-ones, and different reaction systems (Brønsted acids/electrophiles with solvents) afforded different substituted benzenes. Furthermore, the halogenated moiety and alkoxy group can be readily introduced into the benzene in a position which has not been easily obtained previously. |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1021/jo301567p |
| Funding Organization | the National Science Foundation (NSF 21072080);the National Basic Research Program of China (973 Program, 2010CB8-33203);the Fundamental Research Funds for the Central Universities (lzujbky-2012-215) |
| Indexed By | SCI |
| If | 4.564 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19542 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Liang YM(梁永民) |
| Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Yang F,Qiu, Yi-Feng,Ji KG,et al. Divergent Synthesis of Benzene Derivatives: Bronsted Acid Catalyzed and Iodine-Promoted Tandem Cyclization of 5,2-Enyn-1-ones[J]. Journal of Organic Chemistry,2012,77(20):9029-9037. |
| APA | Yang F.,Qiu, Yi-Feng.,Ji KG.,Niu YN.,Ali, Shaukat.,...&梁永民.(2012).Divergent Synthesis of Benzene Derivatives: Bronsted Acid Catalyzed and Iodine-Promoted Tandem Cyclization of 5,2-Enyn-1-ones.Journal of Organic Chemistry,77(20),9029-9037. |
| MLA | Yang F,et al."Divergent Synthesis of Benzene Derivatives: Bronsted Acid Catalyzed and Iodine-Promoted Tandem Cyclization of 5,2-Enyn-1-ones".Journal of Organic Chemistry 77.20(2012):9029-9037. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| jo301567p.pdf（643KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment