Aggregation-Resistant Superparamagnetic Noncovalent Hybrid Multilayer Hollow Microcapsules in High Ionic Strength Media | |
Department | 环境材料与生态化学研究发展中心 |
Liu P(刘鹏)1; Li, Xiaorui1; Mu B(牟斌)2; Du, Pengcheng1; Zhao, Xubo1; Zhong, Zhuliang1; Liu P(刘鹏) | |
2012 | |
Source Publication | Industrial and Engineering Chemistry Research |
ISSN | 0888-5885 |
Volume | 51Issue:43Pages:13875-13881 |
Abstract | In order to avoid the aggregation and/or fusion of the polyelectrolyte multilayer hollow microcapsules self-assembled via the noncovalent bonds, superparamagnetic polyelectrolyte hybrid hollow microcapsules surface-modified with polyethylene glycol (PEG) brushes were designed and fabricated. After the layer-by-layer (LbL) self-assembly of chitosan (CS) and citric acid-modified magnetic nanoparticles (Fe3O4–CA) as the polycation and the hybrid anion on the polystyrene sulfonate microsphere (PSS) templates, respectively, the aldehyde group terminated polyethylene glycol-4000 (APEG) was grafted onto the surface of the superparamagnetic polyelectrolyte hybrid multilayer coated template microspheres via the nucleophilic addition between the aldehyde groups of APEG and the amino groups of CS. Then, the modified superparamagnetic polyelectrolyte hybrid hollow microcapsules were obtained after the templates were removed by dialysis. It was found that the surface PEGylation could prevent aggregation among the hollow microcapsules in the media with high salt concentration by dynamic light scattering (DLS), besides the increase in biocompatibility. The technique developed is expected to realize the application of the polyelectrolyte multilayer hollow microcapsules in real physiological environments. |
Subject Area | 环境材料与生态化学 |
DOI | 10.1021/ie301926m |
Funding Organization | the National Nature Science Foundation of China (Grant No. 20904017) ; the Program for New Century Excellent Talents in University (Grant No. NCET-09-0441) ; the Fundamental Research Funds for the Central Universities (Grant No. lzujbky-2012-k12) |
Indexed By | SCI |
If | 2.206 |
Language | 英语 |
Funding Project | 功能复合材料组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19540 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | Liu P(刘鹏) |
Affiliation | 1.State Key Laboratory of Applied Organic Chemistry and Institute of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China 2.Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China |
Recommended Citation GB/T 7714 | Liu P,Li, Xiaorui,Mu B,et al. Aggregation-Resistant Superparamagnetic Noncovalent Hybrid Multilayer Hollow Microcapsules in High Ionic Strength Media[J]. Industrial and Engineering Chemistry Research,2012,51(43):13875-13881. |
APA | Liu P.,Li, Xiaorui.,Mu B.,Du, Pengcheng.,Zhao, Xubo.,...&Liu P.(2012).Aggregation-Resistant Superparamagnetic Noncovalent Hybrid Multilayer Hollow Microcapsules in High Ionic Strength Media.Industrial and Engineering Chemistry Research,51(43),13875-13881. |
MLA | Liu P,et al."Aggregation-Resistant Superparamagnetic Noncovalent Hybrid Multilayer Hollow Microcapsules in High Ionic Strength Media".Industrial and Engineering Chemistry Research 51.43(2012):13875-13881. |
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ie301926m.pdf(3712KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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