| Supramolecular assemblies formed by cooperative metal coordination and dimerization of the N-(2-pyirimidyl)-N´-(3-pyridyl)urea ligand via hydrogen bonding | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 精细石油化工中间体国家工程研究中心 |
Jia CD(贾传东); Liang JJ(梁建军); Yang J(杨进); Huang XJ(黄晓卷) ; Yang XJ(杨晓娟); Wu B(吴彪); Tang N(唐宁)
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| 2008 | |
| Source Publication | Zeitschrift Fur Anorganische Und Allgemeine Chemie
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| ISSN | 0044-2313 |
| Volume | 634Pages:1210-1214 |
| Abstract | The supramolecular structures of two metal complexes, [CoCl2L2] (1) and [ZnCl2L2] (2), where L＝N-(2-pyrimidyl)-N-(3-pyridyl)urea, are reported. The complexes feature zigzag chains formed by the self-dimerization of the ligand via a pair of Nurea H···Npyrimidyl hydrogen bonds with the R22(8) motif. Only the pyridyl nitrogen atom coordinates to the metal atom whereas the two pyrimidyl N donors are involved in intra- and intermolecular hydrogen bonding interactions. The coordinated Cl atoms do not form any hydrogen bonds with the urea NH groups. The dimerization of the ligand (K＝90 M-1) was investigated by 1H NMR spectroscopy. |
| Keyword | N-(2-pyrimidyl)-n -(3-pyridyl)Urea Supramolecular Structure Hydrogen Bonding Cobalt Zinc |
| Subject Area | 金属有机与超分子催化 |
| Funding Organization | the “Bairen Jihua” project of Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属有机与超分子催化研究组 ; 金属有机功能材料研究组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1952 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Yang XJ(杨晓娟); Wu B(吴彪) |
| Recommended Citation GB/T 7714 | Jia CD,Liang JJ,Yang J,et al. Supramolecular assemblies formed by cooperative metal coordination and dimerization of the N-(2-pyirimidyl)-N´-(3-pyridyl)urea ligand via hydrogen bonding[J]. Zeitschrift Fur Anorganische Und Allgemeine Chemie,2008,634:1210-1214. |
| APA | 贾传东.,梁建军.,杨进.,黄晓卷.,杨晓娟.,...&唐宁.(2008).Supramolecular assemblies formed by cooperative metal coordination and dimerization of the N-(2-pyirimidyl)-N´-(3-pyridyl)urea ligand via hydrogen bonding.Zeitschrift Fur Anorganische Und Allgemeine Chemie,634,1210-1214. |
| MLA | 贾传东,et al."Supramolecular assemblies formed by cooperative metal coordination and dimerization of the N-(2-pyirimidyl)-N´-(3-pyridyl)urea ligand via hydrogen bonding".Zeitschrift Fur Anorganische Und Allgemeine Chemie 634(2008):1210-1214. |
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