| High-yield synthesis of 1,3-Dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 精细石油化工中间体国家工程研究中心 |
Zhang C(张翠); Yang PJ(杨培菊) ; Yang Y(杨月); Huang XJ(黄晓卷); Yang XJ(杨晓娟); Wu B(吴彪)
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| 2008 | |
| Source Publication | Synthetic Communications
 |
| ISSN | 0039-7911 |
| Volume | 38Pages:2349-2356 |
| Abstract | 1,3-Dimesityl-propane-1,3-dione was synthesized in high yield, via a stable intermediate (its aluminum complex) from malonyl dichloride and mesitylene by Friedel–Crafts reaction using anhydrous aluminum chloride as catalyst. The intermediate aluminum complex was isolated and characterized by X-ray diffraction analysis, which decomposed upon reflux in concentrate hydrochloric acid to give the title compound. |
| Keyword | Aluminum Complex Friedel–crafts Reaction 1 Synthesis 3-dimesityl-propane-1 3-dione |
| Subject Area | 金属有机与超分子催化 |
| Funding Organization | the Bairen Jihua program of the Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属有机与超分子催化研究组 ; 金属有机功能材料研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1947 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 精细石油化工中间体国家工程研究中心（ERC） |
| Corresponding Author | Wu B(吴彪) |
| Recommended Citation GB/T 7714 | Zhang C,Yang PJ,Yang Y,et al. High-yield synthesis of 1,3-Dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate[J]. Synthetic Communications,2008,38:2349-2356. |
| APA | 张翠,杨培菊,杨月,黄晓卷,杨晓娟,&吴彪.(2008).High-yield synthesis of 1,3-Dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate.Synthetic Communications,38,2349-2356. |
| MLA | 张翠,et al."High-yield synthesis of 1,3-Dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate".Synthetic Communications 38(2008):2349-2356. |
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| 75_Synthetic Commun.（230KB） | 开放获取 | License | View Application Full Text | |||
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