Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2

doi:10.1021/ol5032156

	Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2
Department	OSSO国家重点实验室
	Shen DY(沈都益)1,2 ; Miao CX(苗成霞)1 ; Xu DQ(徐大乾)1; Xia CG(夏春谷)1 ; Sun W(孙伟)1
	2015
Source Publication	Organic Letters
ISSN	1523-7060
Volume	17 Issue:1 Pages:54-57
Abstract	The manganese complex Mn(S-PMB)(CF₃SO₃)₂ was proven to be highly efficient in the catalytic oxidation of several benzylic and aliphatic secondary alcohols with H₂O₂ as the oxidant and acetic acid as the additive. A maximum turnover number of 4700 was achieved in the alcohol oxidation. In addition, the Hammett analysis unveiled the electrophilic nature of this manganese catalyst with N₄ ligand.
Subject Area	物理化学与绿色催化
DOI	10.1021/ol5032156
Funding Organization	the National Natural Science Foundation of China (Nos. 21133011 ; 21373248)
Indexed By	SCI
If	6.732
Language	英语
Funding Project	生物与仿生催化课题组 ; 均相催化课题组
compositor	第一作者单位
Citation statistics	Cited Times:64[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/19473
Collection	羰基合成与选择氧化国家重点实验室（OSSO）
Affiliation	1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China 2.University of Chinese Academy of Sciences, Beijing 100049, P. R. China
Recommended Citation GB/T 7714	Shen DY,Miao CX,Xu DQ,et al. Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2[J]. Organic Letters,2015,17(1):54-57.
APA	Shen DY,Miao CX,Xu DQ,Xia CG,&Sun W.(2015).Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2.Organic Letters,17(1),54-57.
MLA	Shen DY,et al."Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2".Organic Letters 17.1(2015):54-57.

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