| Lactic acid as an invaluable bio-based solvent for organic reactions | |
| Department | OSSO国家重点实验室 |
| Yang, Jie1; Tan, Jia-Neng1; Gu YL(顾彦龙)1,2; Gu YL(顾彦龙) | |
| 2012 | |
| Source Publication | Green Chemistry
 |
| ISSN | 1463-9262 |
| Volume | 14Issue:12Pages:3304-3317 |
| Abstract | Lactic acid was used, for the first time, as a bio-based green solvent to promote some organic reactions, such as three-component reactions of styrenes, formaldehyde and an active phenolic compound or N,N-dialkylacetoacetamides, three-component reactions of diethyl acetylenedicarboxylate, anilines and aromatic aldehydes, aniline-catalyzed condensations between salicylaldehydes and diethyl acetylenedicarboxylate, and the synthesis of substituted quinolines through Friedlander annulation between 2'-aminoacetophenone and 1,3-dicarbonyl compounds. In these reactions, lactic acid solvent exhibited many advantages including bio-based origin, superior synthetic efficiency, ease of isolating the product and good recyclability of the reaction medium. The concept of using lactic acid as a green solvent not only enriches the diversity and versatility of bio-based green solvents, but also offers us an effective means for designing environmentally benign synthetic systems. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c2gc36083g |
| Funding Organization | National Natural Science Foundation of China (21173089);new Century Excellent Talents in the University of China (NCET-10-0383);Chutian Scholar Program of the Hubei provincial goverment;the Specialized Research Fund for the Doctoral Program of Higher Education (20090142120081) |
| Indexed By | SCI |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19327 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Gu YL(顾彦龙) |
| Affiliation | 1.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Inst Phys Chem & Ind Catalysis, Hubei Key Lab Mat Chem & Serv Failure, Wuhan 430074, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Yang, Jie,Tan, Jia-Neng,Gu YL,et al. Lactic acid as an invaluable bio-based solvent for organic reactions[J]. Green Chemistry,2012,14(12):3304-3317. |
| APA | Yang, Jie,Tan, Jia-Neng,Gu YL,&顾彦龙.(2012).Lactic acid as an invaluable bio-based solvent for organic reactions.Green Chemistry,14(12),3304-3317. |
| MLA | Yang, Jie,et al."Lactic acid as an invaluable bio-based solvent for organic reactions".Green Chemistry 14.12(2012):3304-3317. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c2gc36083g.pdf（607KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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