The Effect of the Spacer of Bis(biurea) Ligands on the Structure of A(2)L(3)-type (A = anion) Phosphate Complexes | |
Department | OSSO国家重点实验室 |
Wu B(吴彪)1; Li SG(李少光)2; Lei, Yibo1; Hu, Huaiming1; Amadeu, Nader de Sousa3; Janiak, Christoph3; Mathieson, Jennifer S.4; Long, De-Liang4; Cronin, Leroy4; Yang XJ(杨晓娟)1; Wu B(吴彪); Yang XJ(杨晓娟) | |
2015 | |
Source Publication | Chemistry - A European Journal |
ISSN | 0947-6539 |
Volume | 21Issue:6Pages:2588-2593 |
Abstract | By tuning the length and rigidity of the spacer of bis(biurea) ligands L, three structural motifs of the A2L3 complexes (A represents anion, here orthophosphate PO43−), namely helicate, mesocate, and mono-bridged motif, have been assembled by coordination of the ligand to phosphate anion. Crystal structure analysis indicated that in the three complexes, each of the phosphate ions is coordinated by twelve hydrogen bonds from six surrounding urea groups. The anion coordination properties in solution have also been studied. The results further demonstrate the coordination behavior of phosphate ion, which shows strong tendency for coordination saturation and geometrical preference, thus allowing for the assembly of novel anion coordination-based structures as in transition-metal complexes. |
Keyword | Anion Coordination Helicates Mesocates Oligourea Phosphates |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/chem.201405235 |
Funding Organization | the National Natural Science Foundation of China (21271149;21325102) |
Indexed By | SCI |
If | 5.771 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19307 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Wu B(吴彪); Yang XJ(杨晓娟) |
Affiliation | 1.NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Coll Chem & Mat Sci, Xian 710069, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 3.Univ Dusseldorf, Inst Anorgan Chem & Strukturchem, D-40225 Dusseldorf, Germany 4.Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland |
Recommended Citation GB/T 7714 | Wu B,Li SG,Lei, Yibo,et al. The Effect of the Spacer of Bis(biurea) Ligands on the Structure of A(2)L(3)-type (A = anion) Phosphate Complexes[J]. Chemistry - A European Journal,2015,21(6):2588-2593. |
APA | Wu B.,Li SG.,Lei, Yibo.,Hu, Huaiming.,Amadeu, Nader de Sousa.,...&杨晓娟.(2015).The Effect of the Spacer of Bis(biurea) Ligands on the Structure of A(2)L(3)-type (A = anion) Phosphate Complexes.Chemistry - A European Journal,21(6),2588-2593. |
MLA | Wu B,et al."The Effect of the Spacer of Bis(biurea) Ligands on the Structure of A(2)L(3)-type (A = anion) Phosphate Complexes".Chemistry - A European Journal 21.6(2015):2588-2593. |
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