From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C-H Bonds | |
Department | OSSO国家重点实验室 |
Li, Wu1; Duan, Zhengli1; Zhang, Xueye1; Zhang, Heng1; Wang, Mengfan1; Jiang, Ru1; Zeng, Hongyao3; Liu C(刘超)1; Lei AW(雷爱文)1,2; Lei AW(雷爱文) | |
2015 | |
Source Publication | Angewandte Chemie International Edition |
ISSN | 1433-7851 |
Volume | 54Issue:6Pages:1893-1896 |
Abstract | A novel palladium-catalyzed CH double carbonylation introduces two adjacent carbonyl groups for the synthesis of isatins from readily available anilines. The reaction proceeds under atmospheric pressure of CO with high regioselectivity and without any additives. Density functional theory investigations indicate that the palladium-catalyzed double carbonylation catalytic cycle is plausible. |
Keyword | C-h Activation Carbonylation Heterocycles Oxidation Palladium |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/anie.201410321 |
Funding Organization | the 973 Program (2011CB808600;2012CB725302);the National Natural Science Foundation of China (21390400;21025206;21272180;21302148);the Research Fund for the Doctoral Program of Higher Education of China (20120141130002);the Program for Changjiang Scholars and Innovative Research Team in University (IRT1030);the Program of Introducing Talents of Discipline to Universities of China (111 Program) |
Indexed By | SCI |
If | 11.709 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19303 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Lei AW(雷爱文) |
Affiliation | 1.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 3.Leshan Normal Univ, Coll Chem, Leshan 614000, Sichuan, Peoples R China |
Recommended Citation GB/T 7714 | Li, Wu,Duan, Zhengli,Zhang, Xueye,et al. From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C-H Bonds[J]. Angewandte Chemie International Edition,2015,54(6):1893-1896. |
APA | Li, Wu.,Duan, Zhengli.,Zhang, Xueye.,Zhang, Heng.,Wang, Mengfan.,...&雷爱文.(2015).From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C-H Bonds.Angewandte Chemie International Edition,54(6),1893-1896. |
MLA | Li, Wu,et al."From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C-H Bonds".Angewandte Chemie International Edition 54.6(2015):1893-1896. |
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Li_et_al-2015-Angewa(366KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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