LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C-H Bonds
DepartmentOSSO国家重点实验室
Li, Wu1; Duan, Zhengli1; Zhang, Xueye1; Zhang, Heng1; Wang, Mengfan1; Jiang, Ru1; Zeng, Hongyao3; Liu C(刘超)1; Lei AW(雷爱文)1,2; Lei AW(雷爱文)
2015
Source PublicationAngewandte Chemie International Edition
ISSN1433-7851
Volume54Issue:6Pages:1893-1896
Abstract

A novel palladium-catalyzed C[BOND]H double carbonylation introduces two adjacent carbonyl groups for the synthesis of isatins from readily available anilines. The reaction proceeds under atmospheric pressure of CO with high regioselectivity and without any additives. Density functional theory investigations indicate that the palladium-catalyzed double carbonylation catalytic cycle is plausible.

KeywordC-h Activation Carbonylation Heterocycles Oxidation Palladium
Subject Area物理化学与绿色催化
DOI10.1002/anie.201410321
Funding Organizationthe 973 Program (2011CB808600;2012CB725302);the National Natural Science Foundation of China (21390400;21025206;21272180;21302148);the Research Fund for the Doctoral Program of Higher Education of China (20120141130002);the Program for Changjiang Scholars and Innovative Research Team in University (IRT1030);the Program of Introducing Talents of Discipline to Universities of China (111 Program)
Indexed BySCI
If11.709
Language英语
compositor第二作者单位
Citation statistics
Cited Times:102[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/19303
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorLei AW(雷爱文)
Affiliation1.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
3.Leshan Normal Univ, Coll Chem, Leshan 614000, Sichuan, Peoples R China
Recommended Citation
GB/T 7714
Li, Wu,Duan, Zhengli,Zhang, Xueye,et al. From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C-H Bonds[J]. Angewandte Chemie International Edition,2015,54(6):1893-1896.
APA Li, Wu.,Duan, Zhengli.,Zhang, Xueye.,Zhang, Heng.,Wang, Mengfan.,...&雷爱文.(2015).From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C-H Bonds.Angewandte Chemie International Edition,54(6),1893-1896.
MLA Li, Wu,et al."From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C-H Bonds".Angewandte Chemie International Edition 54.6(2015):1893-1896.
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