| Bronsted acid ionic liquid-catalyzed reductive Friedel-Crafts alkylation of indoles and cyclic ketones without using an external reductant | |
| Department | OSSO国家重点实验室 |
| Taheri, Amir1; Lai, Bingbing1; Cheng Chenga1; Gu YL(顾彦龙)1,2; Gu YL(顾彦龙) | |
| 2015 | |
| Source Publication | Green Chemistry
 |
| ISSN | 1463-9262 |
| Volume | 17Issue:2Pages:812-816 |
| Abstract | In the absence of an external reductant, C3-cycloalkylated indole could be synthesized through reductive alkylation of indole with cyclic ketone using a sulfonyl-functionalized Brønsted acid ionic liquid as a catalyst. Water generated in the initial stage of the reaction played a key role in rendering the reductive coupling possible. The reaction proceeds most likely in a radical way. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c4gc01299b |
| Funding Organization | National Natural Science Foundation of China (21173089;21373093);Chutian Scholar Program of the Hubei Provincial Government and the Cooperative Innovation Center of Hubei Province; the Fundamental Research Funds for the Central Universities of China (2014ZZGH019) |
| Indexed By | SCI |
| If | 8.506 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19295 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Gu YL(顾彦龙) |
| Affiliation | 1.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Key Lab Large Format Battery Mat & Syst, Minist Educ, Wuhan 430074, Peoples R China 2.Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Taheri, Amir,Lai, Bingbing,Cheng Chenga,et al. Bronsted acid ionic liquid-catalyzed reductive Friedel-Crafts alkylation of indoles and cyclic ketones without using an external reductant[J]. Green Chemistry,2015,17(2):812-816. |
| APA | Taheri, Amir,Lai, Bingbing,Cheng Chenga,Gu YL,&顾彦龙.(2015).Bronsted acid ionic liquid-catalyzed reductive Friedel-Crafts alkylation of indoles and cyclic ketones without using an external reductant.Green Chemistry,17(2),812-816. |
| MLA | Taheri, Amir,et al."Bronsted acid ionic liquid-catalyzed reductive Friedel-Crafts alkylation of indoles and cyclic ketones without using an external reductant".Green Chemistry 17.2(2015):812-816. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c4gc01299b.pdf（352KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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