| DOSS- Based QAILs: As Both Neat Lubricants and Lubricant Additives with Excellent Tribological Properties and Good Detergency | |
| Department | 固体润滑国家重点实验室 |
Fan MJ(凡明锦)1 ; Yang, Desuo1; Wang, Xiaoling1; Liu WM(刘维民)2; Fu, Hanzhuo3; Fan MJ(凡明锦)
| |
| 2014 | |
| Source Publication | Industrial and Engineering Chemistry Research
 |
| ISSN | 0888-5885 |
| Volume | 53Issue:46Pages:17952-17960 |
| Abstract | DOSS– (dioctyl sulfosuccinate) based quaternary ammonium ionic liquids (QAILs) were synthesized and used as both neat lubricants and lubricant additives. The influence of structure on their miscibility, thermal stability, and tribological property was discussed. These QAILs are low cost as compared with conventional halogen-containing ionic liquids (ILs). They are noncorrosive and hydrolysis stable because of their halogen-free characteristics. The tribological properties of these QAILs as neat lubricants for steel/steel and steel/copper contacts are found to be better than conventional halogen-containing ILs 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (L-F104) and far better than traditional synthetic lubricant poly-α-olefin (PAO). Moreover, oil-soluble ILs were obtained by properly adjusting the chain length and cation asymmetry of these QAILs, which can be easily dissolved in nonpolar synthetic-oil PAO. They are found to be effective lubricant additives for improving the friction-reducing and antiwear properties of PAO. It is a great advantage as compared with conventional ILs, which have extremely low solubility in PAO and are difficult to be used as lubricant additives for this kind of base oil. Furthermore, the coking test results indicated that the synthesized QAILs have high deterging ability when used as lubricant additives for PAO. Thus, they can restrain carbonaceous deposition as well as oil sludge and varnish formation on the metal contacts during the sliding process. They can also disperse, loosen, and remove the already formed harmful substances and keep the metal contacts clean. The present work may make obvious progress toward preparing low cost, noncorrosive, and environmentally benign IL lubricants in lubrication engineering. |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1021/ie502849w |
| Funding Organization | NSFC 51105353;the State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences |
| Indexed By | SCI |
| If | 2.587 |
| Language | 英语 |
| Funding Project | 空间润滑材料组 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19276 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Fan MJ(凡明锦) |
| Affiliation | 1.Baoji Univ Arts & Sci, Coll Chem & Chem Engn, Shaanxi Key Lab Phytochem, Baoji 721013, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 3.Florida Int Univ, Dept Chem & Biochem, Miami, FL 33172 USA |
| Recommended Citation GB/T 7714 | Fan MJ,Yang, Desuo,Wang, Xiaoling,et al. DOSS- Based QAILs: As Both Neat Lubricants and Lubricant Additives with Excellent Tribological Properties and Good Detergency[J]. Industrial and Engineering Chemistry Research,2014,53(46):17952-17960. |
| APA | Fan MJ,Yang, Desuo,Wang, Xiaoling,Liu WM,Fu, Hanzhuo,&凡明锦.(2014).DOSS- Based QAILs: As Both Neat Lubricants and Lubricant Additives with Excellent Tribological Properties and Good Detergency.Industrial and Engineering Chemistry Research,53(46),17952-17960. |
| MLA | Fan MJ,et al."DOSS- Based QAILs: As Both Neat Lubricants and Lubricant Additives with Excellent Tribological Properties and Good Detergency".Industrial and Engineering Chemistry Research 53.46(2014):17952-17960. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| ie502849w.pdf（4468KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment