| Diels-Alder/Oxidative Aromatization Approach towards the All- Carbon DEF Tricyclic Skeleton of Daphenylline | |
| Department | OSSO国家重点实验室 |
| Li HL(李辉林)1; Qiu, Yangcheng1; Zhao CG(赵常贵)1; Yuan, Ziyun1; Xie XG(谢新刚)1; She XG(厍学功)1,2; She XG(厍学功) | |
| 2014 | |
| Source Publication | Chemistry - An Asian Journal
 |
| ISSN | 1861-4728 |
| Volume | 9Issue:5Pages:1274-1277 |
| Abstract | Daphenylline is a recently isolated Daphniphyllum alkaloid with an unprecedented novel hexacyclic scaffold. In this study, the synthesis of the fused all-carbon DEF tricyclic skeleton of daphenylline has been accomplished. Key steps of the reported sequence involve Evans asymmetric allylation, aldol condensation, Diels-Alder reaction, and oxidative aromatization reactions. The developed strategy might lead to the total synthesis of daphenylline. |
| Keyword | Alkaloids Aromatization Daphenylline Diels-alder Natural Products |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/asia.201400002 |
| Funding Organization | the NSFC (21125207;21372103;21102062);the MOST (2010CB833200);FRFCU (lzujbky-2013-49;lzujbky-2013-ct02) |
| Indexed By | SCI |
| If | 4.587 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19263 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | She XG(厍学功) |
| Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Dept Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
| Recommended Citation GB/T 7714 | Li HL,Qiu, Yangcheng,Zhao CG,et al. Diels-Alder/Oxidative Aromatization Approach towards the All- Carbon DEF Tricyclic Skeleton of Daphenylline[J]. Chemistry - An Asian Journal,2014,9(5):1274-1277. |
| APA | Li HL.,Qiu, Yangcheng.,Zhao CG.,Yuan, Ziyun.,Xie XG.,...&厍学功.(2014).Diels-Alder/Oxidative Aromatization Approach towards the All- Carbon DEF Tricyclic Skeleton of Daphenylline.Chemistry - An Asian Journal,9(5),1274-1277. |
| MLA | Li HL,et al."Diels-Alder/Oxidative Aromatization Approach towards the All- Carbon DEF Tricyclic Skeleton of Daphenylline".Chemistry - An Asian Journal 9.5(2014):1274-1277. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Chemistry - An Asian（242KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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